Journal of the American Chemical Society p. 10293 - 10298 (2008)
Update date:2022-08-05
Topics:
Navarro, Ismael
Basset, Jean-Francois
Hebbe, Severine
Major, Sarah M.
Werner, Thomas
Howsham, Catherine
Braeckow, Jan
Barrett, Anthony G. M.
Diketo-1,3-dioxin-2-ones underwent retro-Diels-Alder reaction on heating in toluene at 110°C to generate α,γ,ε-triketo-ketenes. These were trapped with alcohols to provide 2,4,6-triketocarboxylates, which were smoothly aromatized by sequential reaction wi
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