104516-22-5Relevant academic research and scientific papers
REGIOCHEMISTRY OF THE ALKYLATION OF SELENIUM STABILIZED ALLYLIC ANIONS
Hevesi, L.,Nsunda, K. M.,Renard, M.
, p. 1039 - 1044 (2007/10/02)
Selenium substituted allyl lithiums react with alkyl halides or benzaldehyde to produce alkylation products in good yield.The regiochemistry of this reaction is found to bear similarities with that of the thio-analogs in that it depends largely on the nature of the alkylating agent and on the reaction conditions; it is further complicated by the occurrence of the allyl selenide rearrangement discovered recently.
PREPARATION OF 3-HYDROXYL-VINYL SELENIDES AND 1,3-BIS(SELENO)-PROPENES
Renard, M.,Hevesi, L.
, p. 5939 - 5954 (2007/10/02)
Z and E 3-hydroxy-vinyl selenides can be prepared with very high stereoselectivity respectively by nucleophilic addition of selenolates to propargyl alcohols and by selenylation followed by LiAlH4 reduction of the same propargyl alcohols. 1,3-Bis(seleno)-
