30197-13-8Relevant academic research and scientific papers
VINYL RADICAL GENERATION WITH SELENOBORANE AND ITS APPLICATION TO CYCLIZATION REACTION OF ENYNES
Kataoka, Tadashi,Yoshimatsu, Mitsuhiro,Shimizu, Hiroshi,Hori, Mikio
, p. 5927 - 5930 (2007/10/02)
Tris(methylseleno)- and tris(phenylseleno)boranes added to acetylenes to afford methylseleno- and phenylseleno-substituted Z-vinylselenides in high yields.The addition reactions proceeded by way of free radicals and were applied to cyclization reactions o
Selenium in Organic Synthesis: A Novel Route to 1-Phenylselenobutadienes and 1,4-Dicarbonyl Compounds
Comasseto, J. V.,Brandt, C. A.
, p. 146 - 149 (2007/10/02)
Two approaches to 1-phenylseleno-1,3-butadienes 5 are reported, via phenylselenoalkenylidene phosphoranes and phenylselenoalkenals, respectively. 1,4-Dicarbonyl compounds are prepared from the 1-phenylselenobutadienes or from the phenylselenoalkenals.
PREPARATION OF 3-HYDROXYL-VINYL SELENIDES AND 1,3-BIS(SELENO)-PROPENES
Renard, M.,Hevesi, L.
, p. 5939 - 5954 (2007/10/02)
Z and E 3-hydroxy-vinyl selenides can be prepared with very high stereoselectivity respectively by nucleophilic addition of selenolates to propargyl alcohols and by selenylation followed by LiAlH4 reduction of the same propargyl alcohols. 1,3-Bis(seleno)-
