104545-86-0

Upstream product

• 110079-96-4 [(4S,5R)-5-((R)-1-Hydroxy-ethyl)-2-trichloromethyl-4,5-dihydro-oxazol-4-yl]-acetic acid methyl ester 
• 110079-92-0 (R)-3-((2S,3R)-3-Methyl-oxiranyl)-3-(2,2,2-trichloro-acetylamino)-propionic acid methyl ester 
• 75712-50-4 3-Amino-3-((4R,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-propionamide 
• 38280-94-3 4,5-O-isopropylidene-erythro-hex-2-enoic acid methyl ester 
• 75812-85-0 (Z)-3-Amino-hex-4-enoic acid methyl ester; hydrochloride 
• 110079-91-9 methyl (Z)-3-(N-trichloroacetamido)-4-hexanoate 

Downstream Products

• 75812-90-7 DL-xylo-3-(Benzoylamino)-2,3,6-trideoxyhexanoic acid γ-lactone 
• 110170-04-2 methyl xylo-3-(benzoylamino)-2,3,6-trideoxyhexonate 

Relevant academic research and scientific papers

Stereochemistry of the Epoxidations of Acyclic Allylic Amides. Applications toward the Synthesis of 2,3,6-Trideoxy-3-aminohexoses

The stereochemistry of the epoxidation of several acyclic allylic amides is described.Diastereoselectivity in the (Z)-allylic amide series (compound 1) proved to be dependent both on the amide functionality and epoxidation reagent.The threo epoxide 3 was

THE SYNTHESIS OF 3-ACETAMIDO-2,3,5,6-TETRADEOXY-5-FLUORO-D,L-ribo-HEXOFURANOSE BY THE DIRECT FLUORINATION OF METHYL 3-ACETAMIDO-2,3,6-TRIDEOXY-D,L-arabino-HEXOPYRANOSIDE (METHYL N-ACETYL-D,L-ACOSAMINIDE)

3-Acetamido-2,3,5,6-tetradeoxy-5-fluoro-D,L-ribo-hexofuranose was synthesized by direct, fluorinative dehydroxylation of methyl 3-acetamido-2,3,6-trideoxy-D,L-arabino-hexopyranoside with sulfur tetrafluoride-hydrogen fluoride.The furanose form and the ribo configuration, indicated by 13C- and 1H-n. m. r. spectroscopy, respectively, were confirmed by a single-crystal, X-ray diffraction study.