Stereochemistry of the Epoxidations of Acyclic Allylic Amides. Applications toward the Synthesis of 2,3,6-Trideoxy-3-aminohexoses

DOI: 10.1021/jo00232a014

Source and publish data:

Journal of Organic Chemistry p. 5127 - 5136 (1987)

Update date:2022-08-04

Topics:

Authors:

Roush, William R.

Straub, Julie A.

Brown, Richard J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00232a014

The stereochemistry of the epoxidation of several acyclic allylic amides is described.Diastereoselectivity in the (Z)-allylic amide series (compound 1) proved to be dependent both on the amide functionality and epoxidation reagent.The threo epoxide 3 was

Full text of DOI:10.1021/jo00232a014

Products guided by the article

Product name:(4S,5R)-4-Amino-5-((R)-1-hydroxy-ethyl)-dihydro-furan-2-one

Cas No:104545-86-0

R&D Labs maybe for 104545-86-0

GN chemicals co.,ltd

Contact:86 311 85902108 / 85902109

Address:room 1001-1005 ,huanghe Road ,shijiazhuang ,China
Shanghai PurityPE Biotechnology Co., Ltd.

website:http://www.puritype.com

Contact:+86-18917347808; +86-15921887593

Address:Room 907, Tongda Venture Building, No.1, Lane 600, Tianshan Road, Shanghai, China
Exploiter Molybdenum Co.,Ltd

Contact:86-379-63338609

Address:Jiudian Village,Deting Town,Song County,Luoyang
Xiamen Hisunny Chemical Co.,Ltd

website:http://www.hisunnychem.com

Contact:+86-592-3327115

Address:Unit 603,No.879,Xiahe Road,Meixin Building,Xiamen,China
Hunan Shineway Enterprise Co., Ltd.

Contact:+86-731-86303875

Address:118, Huanghua International Airport Road, Huanghua Town, Changsha, Hunan 410137, China

Relevant to this article

Synthesis of isoquinoline-3-carboxylates and benzocyclobutanes via reaction of 2-amidoacrylate esters with arynes

Doi:10.1055/s-2008-1072723
(2008)
Palladium-catalysed oxidation of alcohols with carbon tetrachloride, formation of 4,4,4-trichloro ketones from allylic alcohols and carbon tetrachlorid

Doi:10.1016/S0040-4020(01)91368-7
(1985)
Synthesis of N,N-disubstituted phosphoramidates via a Lewis acid-catalyzed phosphorimidate rearrangement

Doi:10.1039/b802030b
(2008)
β-Halovinylsilanes in oligoyne synthesis: a fluoride-catalysed unmasking of alkynes from β-fluorovinylsilanes

Doi:10.1016/j.tetlet.2008.05.081
(2008)
Generation of Alkoxyl Radicals by Photoredox Catalysis Enables Selective C(sp³)-H Functionalization under Mild Reaction Conditions

Doi:10.1002/anie.201510014
(2016)
Tandem olefin metathesis-elimination reactions. A new route to doubly unsaturated carbonyl derivatives

Doi:10.1016/j.tet.2008.04.027
(2008)

Article Doi