104564-69-4

Basic information

• Product Name: tributyl benzene-1,3,5-tricarboxylate
• Synonyms: tributyl benzene-1,3,5-tricarboxylate
• CAS NO: 104564-69-4
• Molecular Weight: 378.466
• Mol File: 104564-69-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tributyl benzene-1,3,5-tricarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: tributyl benzene-1,3,5-tricarboxylate(104564-69-4)
• EPA Substance Registry System: tributyl benzene-1,3,5-tricarboxylate(104564-69-4)

Safety Data

• Hazardous Substances Data: 104564-69-4(Hazardous Substances Data)

Upstream product

• 626-39-1 1,3,5-trisbromobenzene 
• 201230-82-2 carbon monoxide 
• 71-36-3 butan-1-ol 
• 16722-19-3 β-n-Butoxyacrylsaeure-n-butylester 

Relevant articles and documents

Palladium-Catalyzed Butoxycarbonylation of Polybromo(hetero)arenes: A Practical Method for the Preparation of (Hetero)arenepolycarboxylates and -carboxylic Acids

The palladium-catalyzed alkoxycarbonylation of polybromo (hetero)arenes was investigated systematically. The results show that cheap and readily available in situ Pd(OAc) 2/ rac -BINAP catalyst can catalyze the butoxycarbonylation of various polybromo(hetero)arenes efficiently, and gave (hetero)arenepolycarboxylates with moderate to high yield (59-94%). Using this method, two new compounds, 4,4'-bis(butoxycarbonyl)-1,1'-bi-2-naphthol and dibutyl [2,2'-bipyrimidine]-5,5'-dicarboxylate, are reported for the first time. In addition, the gram-scale preparation of carboxylate and carboxylic acids was successful performed by butoxycarbonylation followed by hydrolysis. This shows the wide scope of substrates and practical applications of the Pd(OAc) 2/ rac -BINAP catalytic system. Moreover, these carboxylic acids and carboxylates can be used as ligands or structural units to construct MOFs, metal complexes, and COFs etc.