104581-50-2Relevant academic research and scientific papers
Copper-catalyzed arylative meyer-schuster rearrangement of propargylic alcohols to complex enones using diaryliodonium salts
Collins, Beatrice S. L.,Suero, Marcos G.,Gaunt, Matthew J.
, p. 5799 - 5802 (2013)
Free choice: A copper-catalyzed arylative Meyer-Schuster rearrangement is described. The reaction is compatible with a range of substituted propargylic alcohols and diaryliodonium salts and delivers complex trisubstituted enone products selectively as the
Facile one-pot synthesis of functionalized acetylenes from aryl and heteroaryl aldehydes using lithium trimethylsilyldiazomethane
Hari, Yoshiyuki,Date, Koji,Aoyama, Toyohiko
, p. 545 - 552 (2007)
The reaction of aryl and heteroaryl aldehydes with lithium trimethylsilyldiazomethane followed by treatment with n-BuLi and then electrophiles in one-pot efficiently afforded functionalized acetylenes.
