1046093-72-4Relevant articles and documents
CAN-mediated highly regio- and stereoselective oxidation of vinylidenecyclopropanes: A novel method for the synthesis of unsymmetrical divinyl ketone and functional enone derivatives
Su, Chenliang,Huang, Xian,Liu, Qingyang
, p. 6421 - 6424 (2008/12/22)
(Chemical Equation Presented) CAN-mediated oxidative rearrangement of various vinylidenecyclopropanes under mild conditions generates unsymmetrical divinyl ketone and functional enone derivatives in moderate to good yields with excellent regio- and stereoselectivities. The reaction mechanism was investigated on the basis of an oxygen-18 tracer experiment.