10464-67-2

Basic information

• Product Name: ACETIC ACID 1-IMIDAZOL-1-YL-ETHYL ESTER
• Synonyms: 1-(1-IMIDAZOLYL)ETHYL ACETATE;ACETIC ACID 1-IMIDAZOL-1-YL-ETHYL ESTER
• CAS NO: 10464-67-2
• Molecular Formula: C₇H₁₀N₂O₂
• Molecular Weight: 154.168
• Mol File: 10464-67-2.mol
• Article Data: 11

Chemical Properties

• Appearance: /
• CAS DataBase Reference: ACETIC ACID 1-IMIDAZOL-1-YL-ETHYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: ACETIC ACID 1-IMIDAZOL-1-YL-ETHYL ESTER(10464-67-2)
• EPA Substance Registry System: ACETIC ACID 1-IMIDAZOL-1-YL-ETHYL ESTER(10464-67-2)

Safety Data

• Hazardous Substances Data: 10464-67-2(Hazardous Substances Data)

Upstream product

• 2466-76-4 N-Acetylimidazole 
• 75-07-0 acetaldehyde 
• 288-32-4 1H-imidazole 
• 108-05-4 vinyl acetate 

Downstream Products

• 1072-63-5 1-vinylimidazole 

Relevant articles and documents

Potassium phosphate promoted aza-Markovnikov addition of N-heterocycles to vinyl esters

Anhydrous potassium phosphate promoted the aza-Markovnikov addition of a variety of N-heterocycles to vinyl esters in DMF at room temperature in moderate to excellent yields. Georg Thieme Verlag Stuttgart.

Markovnikov addition of vinyl acetate with azoles catalyzed by potassium tert-butoxide

A simple and efficient methodology for Markovnikov addition of azoles with vinyl acetate catalyzed by potassium tert-butoxide is described. N-heterocyclic compounds are synthesized from simple and commercially available starting materials under mild conditions in high yields.

Synthesis of N-vinylazoles from vinyl acetate without using mercury catalysts

N-Vinyl-substituted pyrazole, 3(5)-methylpyrazole, imidazole, and 1,2,4-triazole were synthesized by addition of the corresponding azoles to vinyl acetate under conditions of phase-transfer catalysis, followed by pyrolysis of N-(1-acetoxyethyl)azoles thus formed at 350-400°C in the presence of water.

Solvent-free aza-Markovnikov and aza-Michael additions promoted by a catalytic amount of imidazolide basic ionic liquids

A family of imidazolide ionic liquids were synthesized and characterized. These ionic liquids combined the virtues of strong basicity and relatively good thermal stability. Catalytic properties of these imidazolide ionic liquids were investigated and satisfactory yield was achieved when 2.0 mol % of [Bmim]Im was used as catalyst for aza-Markovnikov addition under solvent-free condition at room temperature in one hour. Experimental results show that a hydrogen bond is not formed between [Bmim]Im/imidazole and vinyl ester, and its existence is not necessary for the [Bmim]Im catalyzed aza-Markovnikov addition either. A possible mechanism for [Bmim]Im-catalyzed aza-Markovnikov addition was proposed. The use of imidazolide ionic liquids in aza-Michael addition was investigated as well.

Promiscuous acylases-catalyzed Markovnikov addition of N-heterocycles to vinyl esters in organic media

Three acylases, including D-aminoacylase from Escherichia coli, acylase "Amano" from Aspergillus oryzae and immobilized penicillin G acylase from Escherichia coli have been found to possess novel activity to catalyze the Markovnikov addition reaction of N

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