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108-05-4

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Product FOB Price Min.Order Supply Ability Supplier
Vinyl Acetate Monomer
Cas No: 108-05-4
USD $ 1600.0-1600.0 / Kilogram 190 Kilogram 300 Metric Ton/Day Shandong Yanshuo Chemical Co., Ltd. Contact Supplier
Vinyl acetate
Cas No: 108-05-4
USD $ 1.0-2.0 / Metric Ton 1 Metric Ton 10 Metric Ton/Day Hangzhou Keyingchem Co.,Ltd Contact Supplier
Vinyl acetate Manufacturer/High quality/Best price/In stock
Cas No: 108-05-4
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
Top purity Vinyl acetate with high quality and best price cas:108-05-4
Cas No: 108-05-4
USD $ 3.0-10.0 / Kilogram 1 Kilogram 99999 Kilogram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
ethenyl acetate
Cas No: 108-05-4
USD $ 1.0-2.0 / Metric Ton 1 Metric Ton 100 Metric Ton/Week Hebei yanxi chemical co.,LTD. Contact Supplier
Vinyl Acetate MonoMer (stabilized with HQ)
Cas No: 108-05-4
No Data 1 Kilogram 1 Metric Ton/Week Henan Allgreen Chemical Co.,Ltd Contact Supplier
Amadis Chemical offer CAS#108-05-4;CAT#A801803
Cas No: 108-05-4
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
Vinyl acetate CAS: 108-05-4
Cas No: 108-05-4
USD $ 1.0-2.0 / Metric Ton 5 Metric Ton 1000 Metric Ton/Year Henan Sinotech Import&Export Corporation Contact Supplier
TIANFUCHEM-- 108-05-4--High purity Vinyl acetate in stock
Cas No: 108-05-4
USD $ 2000.0-2000.0 / Metric Ton 1 Metric Ton 1000 Metric Ton/Day Henan Tianfu Chemical Co., Ltd. Contact Supplier
Vinyl acetate
Cas No: 108-05-4
USD $ 10.0-1000.0 / Gram 10 Gram 8000 Kilogram/Month HUBEI AOKS BIO-TECH CO.,LTD Contact Supplier

108-05-4 Usage

InChI:InChI=1/C4H6O2/c1-3-6-4(2)5/h3H,1H2,2H3

108-05-4 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Aldrich (V1503)  Vinylacetate  contains 3-20 ppm hydroquinone as inhibitor, ≥99% 108-05-4 V1503-18L 3,229.20CNY Detail
Aldrich (V1503)  Vinylacetate  contains 3-20 ppm hydroquinone as inhibitor, ≥99% 108-05-4 V1503-2.5L 618.93CNY Detail
Aldrich (V1503)  Vinylacetate  contains 3-20 ppm hydroquinone as inhibitor, ≥99% 108-05-4 V1503-1L 355.68CNY Detail
Aldrich (V1503)  Vinylacetate  contains 3-20 ppm hydroquinone as inhibitor, ≥99% 108-05-4 V1503-25ML 238.68CNY Detail
Sigma-Aldrich (Y0000793)  Vinylacetate  European Pharmacopoeia (EP) Reference Standard 108-05-4 Y0000793 1,880.19CNY Detail
Supelco (40327)  Vinylacetatesolution  certified reference material, 5000 μg/mL in acetonitrile 108-05-4 000000000000040327 452.79CNY Detail
Supelco (4S8486)  Vinylacetate  analytical standard 108-05-4 4S8486 234.00CNY Detail
Supelco (48486)  Vinylacetate  analytical standard 108-05-4 000000000000048486 528.84CNY Detail
Alfa Aesar (A16247)  Vinyl acetate, 99%, stab. with 8-12ppm hydroquinone    108-05-4 2500ml 477.0CNY Detail
Alfa Aesar (A16247)  Vinyl acetate, 99%, stab. with 8-12ppm hydroquinone    108-05-4 500ml 228.0CNY Detail
Alfa Aesar (A16247)  Vinyl acetate, 99%, stab. with 8-12ppm hydroquinone    108-05-4 100ml 157.0CNY Detail
TCI America (A0045)  Vinyl Acetate Monomer (stabilized with HQ)  >99.0%(GC) 108-05-4 500mL 136.00CNY Detail

108-05-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name vinyl acetate

1.2 Other means of identification

Product number -
Other names Acetic acid ethenyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:108-05-4 SDS

108-05-4Synthetic route

ethylene glycol diacetate
111-55-7

ethylene glycol diacetate

vinyl acetate
108-05-4

vinyl acetate

Conditions
ConditionsYield
With acetic anhydride; benzenesulfonic acid at 140℃; under 1875.19 Torr; for 0.75h; Inert atmosphere;65.05%
With acetic anhydride; benzenesulfonic acid at 142℃; under 3000.3 Torr; for 0.75h; Inert atmosphere;64.47%
With acetic anhydride; benzenesulfonic acid at 143℃; under 3000.3 Torr; for 0.666667h; Inert atmosphere;64.57%
ethylidene diacetate
542-10-9

ethylidene diacetate

vinyl acetate
108-05-4

vinyl acetate

Conditions
ConditionsYield
With acetic anhydride; benzenesulfonic acid at 145℃; under 2850.29 Torr; for 0.75h; Inert atmosphere;63.51%
With lithium iodide
With acetic anhydride; lithium iodide
at 50 - 200℃; under 11400.8 Torr;
ethylene glycol divinyl ether
764-78-3

ethylene glycol divinyl ether

acetyl iodide
507-02-8

acetyl iodide

A

vinyl acetate
108-05-4

vinyl acetate

B

vinyliodide
593-66-8

vinyliodide

C

2-iodoethyl acetate
627-10-1

2-iodoethyl acetate

Conditions
ConditionsYield
In dichloromethane at 10℃;A 42.8%
B 40.5%
C 54.9%
ethene
74-85-1

ethene

acetic acid
64-19-7

acetic acid

A

vinyl acetate
108-05-4

vinyl acetate

B

2-hydroxyethyl acetate
542-59-6

2-hydroxyethyl acetate

C

ethylene glycol diacetate
111-55-7

ethylene glycol diacetate

Conditions
ConditionsYield
With Pd(MeCN)2Cl(NO2) at 25℃; under 2068.6 Torr; for 4h; Product distribution; various catalysts, times, additives, O2 atmosphere, with 18O containing complex;A 20%
B 50%
C 7%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

acetyl iodide
507-02-8

acetyl iodide

A

vinyl acetate
108-05-4

vinyl acetate

B

1-iodo-butane
542-69-8

1-iodo-butane

C

vinyliodide
593-66-8

vinyliodide

D

acetic acid butyl ester
123-86-4

acetic acid butyl ester

Conditions
ConditionsYield
In dichloromethane at 10℃;A 11.8%
B 12.8%
C 35.8%
D 39.8%
ethene
74-85-1

ethene

potassium acetate
127-08-2

potassium acetate

acetic acid
64-19-7

acetic acid

A

vinyl acetate
108-05-4

vinyl acetate

B

carbon dioxide
124-38-9

carbon dioxide

C

ethyl acetate
141-78-6

ethyl acetate

Conditions
ConditionsYield
With oxygen under 9120.61 Torr; for 16h;A n/a
B 11.57%
C 0.151%
With oxygen under 9120.61 Torr; for 16h;A n/a
B 9.45%
C 0.061%
With oxygen under 9120.61 Torr; for 16h;A n/a
B 9.1%
C 0.049%
β,β-dichlorovinyl acetate
36597-97-4

β,β-dichlorovinyl acetate

A

vinyl acetate
108-05-4

vinyl acetate

B

Z-2-chlorovinyl acetate
103659-54-7

Z-2-chlorovinyl acetate

C

E-2-chlorovinyl acetate
10138-83-7, 103659-54-7

E-2-chlorovinyl acetate

Conditions
ConditionsYield
With tri-n-butyl-tin hydride for 0.5h; Ambient temperature; Irradiation;A 2%
B n/a
C n/a
1-acetoxy-2-(ethyl-acetyl-amino)-ethane
15568-57-7

1-acetoxy-2-(ethyl-acetyl-amino)-ethane

A

vinyl acetate
108-05-4

vinyl acetate

B

N-vinyl-N-ethyl-acetamide
3195-79-7

N-vinyl-N-ethyl-acetamide

C

N-ethylacetamide
625-50-3

N-ethylacetamide

Conditions
ConditionsYield
at 490℃; Erhitzung;
ethylidene diacetate
542-10-9

ethylidene diacetate

acetic anhydride
108-24-7

acetic anhydride

vinyl acetate
108-05-4

vinyl acetate

Conditions
ConditionsYield
With copper (I) acetate; benzenesulfonic acid
acetic anhydride
108-24-7

acetic anhydride

acetaldehyde
75-07-0

acetaldehyde

vinyl acetate
108-05-4

vinyl acetate

Conditions
ConditionsYield
With sulfuric acid
ethylidene diacetate
542-10-9

ethylidene diacetate

copper diacetate
142-71-2

copper diacetate

acetic anhydride
108-24-7

acetic anhydride

benzenesulfonic acid
98-11-3

benzenesulfonic acid

A

vinyl acetate
108-05-4

vinyl acetate

B

acetaldehyde
75-07-0

acetaldehyde

acetic anhydride
108-24-7

acetic anhydride

vinyl acetate
108-05-4

vinyl acetate

Conditions
ConditionsYield
With sodium bei Siedetemperatur;
Ketene
463-51-4

Ketene

acetaldehyde
75-07-0

acetaldehyde

A

vinyl acetate
108-05-4

vinyl acetate

B

3-penten-2-one
625-33-2

3-penten-2-one

Conditions
ConditionsYield
With sulfuric acid
Isopropenyl acetate
108-22-5

Isopropenyl acetate

acetoxysulfonic acid
2308-54-5

acetoxysulfonic acid

acetaldehyde
75-07-0

acetaldehyde

A

vinyl acetate
108-05-4

vinyl acetate

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
at 120℃;
Isopropenyl acetate
108-22-5

Isopropenyl acetate

acetaldehyde
75-07-0

acetaldehyde

vinyl acetate
108-05-4

vinyl acetate

Conditions
ConditionsYield
With 2-sulfo-acetoacetic acid at 120℃;
acetaldehyde
75-07-0

acetaldehyde

acetyl chloride
75-36-5

acetyl chloride

vinyl acetate
108-05-4

vinyl acetate

Conditions
ConditionsYield
With pyridine
With N,N-dimethyl-aniline
ethene
74-85-1

ethene

acetic acid
64-19-7

acetic acid

vinyl acetate
108-05-4

vinyl acetate

acetic acid
64-19-7

acetic acid

acetylene
74-86-2

acetylene

vinyl acetate
108-05-4

vinyl acetate

Conditions
ConditionsYield
at 200 - 220℃; Leiten ueber mit Zink-Salzen impraegnierter Kohle;
at 200 - 220℃; Leiten ueber mit Cadmium-Salzen impraegnierter Kohle;
With complex salts of BF3; boron trifluoride
acetic acid
64-19-7

acetic acid

acetylene
74-86-2

acetylene

A

vinyl acetate
108-05-4

vinyl acetate

B

ethylidene diacetate
542-10-9

ethylidene diacetate

Conditions
ConditionsYield
With acetic anhydride at 40 - 60℃; under 3800 Torr;
pyridine
110-86-1

pyridine

acetyl chloride
75-36-5

acetyl chloride

paraldehyde
1499-02-1

paraldehyde

vinyl acetate
108-05-4

vinyl acetate

quinoline
91-22-5

quinoline

acetic anhydride
108-24-7

acetic anhydride

paraldehyde
1499-02-1

paraldehyde

vinyl acetate
108-05-4

vinyl acetate

acetylene
74-86-2

acetylene

A

vinyl acetate
108-05-4

vinyl acetate

B

ethylidene diacetate
542-10-9

ethylidene diacetate

Conditions
ConditionsYield
With mercury(II) sulfate; acetic acid at 60 - 100℃;
ethene
74-85-1

ethene

A

vinyl acetate
108-05-4

vinyl acetate

B

2-hydroxyethyl acetate
542-59-6

2-hydroxyethyl acetate

C

ethylidene diacetate
542-10-9

ethylidene diacetate

D

ethylene glycol diacetate
111-55-7

ethylene glycol diacetate

E

ethylene glycol
107-21-1

ethylene glycol

F

acetaldehyde
75-07-0

acetaldehyde

Conditions
ConditionsYield
With sodium nitrate; oxygen; sodium chloride; palladium dichloride In acetic acid for 1h; Product distribution; Ambient temperature; presence of sodiun acetate; various pressure: 0.1 to 1.0 MPa; various temperature: 50 to 95 deg C;
acetic acid methyl ester
79-20-9

acetic acid methyl ester

carbon monoxide
201230-82-2

carbon monoxide

A

vinyl acetate
108-05-4

vinyl acetate

B

ethylidene diacetate
542-10-9

ethylidene diacetate

C

acetic anhydride
108-24-7

acetic anhydride

D

acetaldehyde
75-07-0

acetaldehyde

E

acetic acid
64-19-7

acetic acid

F

methyl iodide
74-88-4

methyl iodide

Conditions
ConditionsYield
With ether-phosphane-silyloxy-rhodium; phosphane-silyloxy-platinum at 130℃; under 37503 Torr; for 5h; Product distribution; Mechanism; var. times and temp.; other rhodium complexes;
bromoethyl acetate
927-68-4

bromoethyl acetate

A

vinyl acetate
108-05-4

vinyl acetate

B

ethylene glycol diacetate
111-55-7

ethylene glycol diacetate

C

butane-1,4-diol diacetate
628-67-1

butane-1,4-diol diacetate

D

ethyl acetate
141-78-6

ethyl acetate

Conditions
ConditionsYield
With nickel(II) salen; tetrabutylammonium tetrafluoroborate In acetonitrile Mechanism; electrolysis; other alkyl bromides also in the presence of activated olefins;A 10 % Chromat.
B 21 % Chromat.
C 4 % Chromat.
D 10 % Chromat.
With nickel(II) salen; tetrabutylammonium tetrafluoroborate In acetonitrile electrolysis;A 10 % Chromat.
B 21 % Chromat.
C 4 % Chromat.
D 10 % Chromat.
ethylene glycol diacetate
111-55-7

ethylene glycol diacetate

A

vinyl acetate
108-05-4

vinyl acetate

B

acetic acid
64-19-7

acetic acid

Conditions
ConditionsYield
at 682.6℃; Kinetics;
7-acetoxy-2,3:5,6-dibenzobicyclo<2.2.2>octa-2,5-diene
1871-17-6

7-acetoxy-2,3:5,6-dibenzobicyclo<2.2.2>octa-2,5-diene

A

vinyl acetate
108-05-4

vinyl acetate

B

anthracene
120-12-7

anthracene

Conditions
ConditionsYield
In diphenylether at 250℃; Rate constant;
acetic acid
64-19-7

acetic acid

acetylene
74-86-2

acetylene

A

vinyl acetate
108-05-4

vinyl acetate

B

ethylidene diacetate
542-10-9

ethylidene diacetate

C

acetaldehyde
75-07-0

acetaldehyde

Conditions
ConditionsYield
With mercury(II) diacetate; toluene-4-sulfonic acid at 85℃; for 0.233333h; Kinetics; Mechanism; Product distribution;
2-acetoxyethyl propionate

2-acetoxyethyl propionate

A

vinyl acetate
108-05-4

vinyl acetate

B

vinyl propionate
105-38-4

vinyl propionate

Conditions
ConditionsYield
With methanolate In gas
With methanolate In gas Product distribution; also with base F(1-);
vinyl acetate
108-05-4

vinyl acetate

1,2-dibromoethyl acetate
24442-57-7

1,2-dibromoethyl acetate

Conditions
ConditionsYield
With bromine In tetrachloromethane100%
With propane 3-bromo-1-(triphenylphosphonium) tribromide In dichloromethane at 20℃; for 0.5h;90%
With bromine for 3h;62%
vinyl acetate
108-05-4

vinyl acetate

cyclohexylamine
108-91-8

cyclohexylamine

N-cyclohexylacetamide
1124-53-4

N-cyclohexylacetamide

Conditions
ConditionsYield
at 90℃; for 1h; microwave irradiation;100%
With immobilization of Candida cylindracea lipase In hexane at 55℃; for 15h;99%
With 1-(3-sulfopropyl)pyridinium phosphotungstate In neat (no solvent) at 100℃; for 0.5h; Microwave irradiation;91%
vinyl acetate
108-05-4

vinyl acetate

hexan-1-ol
111-27-3

hexan-1-ol

1-hexyl acetate
142-92-7

1-hexyl acetate

Conditions
ConditionsYield
With dilithium tetra(tert-butyl)zincate In toluene at 0℃; for 1h; Inert atmosphere;100%
With pseudomonas fuorescens lipase immobilized on multiwall carbon nano-tubes at 50℃; for 5h; Green chemistry;99%
With sulfuric acid beim Erhitzen;
With aluminium trichloride at 105℃;
In diethyl ether at 35℃; Candida cylindracea lipase;
vinyl acetate
108-05-4

vinyl acetate

(4-hydroxyphenyl)methanol
623-05-2

(4-hydroxyphenyl)methanol

4-hydroxybenzyl acetate
80767-12-0

4-hydroxybenzyl acetate

Conditions
ConditionsYield
With Candida cylindracea lipase In hexane for 4h;100%
novozyme 435 In acetonitrile at 20℃; for 6h; Enzymatic reaction;99%
iodine at 20℃; for 2h;95%
With porcine pancreatic lipase (PPL, Type II) In tetrahydrofuran at 42 - 45℃; for 48h; Acetylation;80%
With Pseudomonas cepacia PS lipase In di-isopropyl ether at 25℃; for 0.5h;
vinyl acetate
108-05-4

vinyl acetate

p-hydroxyphenethyl alcohol
501-94-0

p-hydroxyphenethyl alcohol

2-(4-hydroxyphenyl)ethyl acetate
58556-55-1

2-(4-hydroxyphenyl)ethyl acetate

Conditions
ConditionsYield
With Candida cylindracea lipase In hexane for 4h;100%
With Candida antartica lipase B In tetrahydrofuran at 20℃; for 4h; Enzymatic reaction; chemoselective reaction;100%
With 1,3-dichlorotetrabutyldistannoxane In tetrahydrofuran at 30℃; for 24h;99%
vinyl acetate
108-05-4

vinyl acetate

salicylic alcohol
90-01-7

salicylic alcohol

2-acetoxymethylphenol
6161-96-2

2-acetoxymethylphenol

Conditions
ConditionsYield
With Candida cylindracea lipase In hexane for 6h;100%
With porcine pancreatic lipase (PPL, Type II) In tetrahydrofuran at 42 - 45℃; for 120h; Acetylation;95%
With Pseudomonas cepacia PS lipase In di-isopropyl ether at 25℃; for 0.25h;
vinyl acetate
108-05-4

vinyl acetate

1,3-dibromoadamantane
876-53-9

1,3-dibromoadamantane

1-acetyladamantane
1660-04-4

1-acetyladamantane

Conditions
ConditionsYield
With Wilkinson's catalyst In dichloromethane at 170℃; for 8h;100%
vinyl acetate
108-05-4

vinyl acetate

2-benzyl-1,3-propanediol
2612-30-8

2-benzyl-1,3-propanediol

(R)-3-acetoxy-2-benzyl-1-propanol
110270-49-0

(R)-3-acetoxy-2-benzyl-1-propanol

Conditions
ConditionsYield
Lipase P;100%
With Pseudomonas cepacia lipase on epoxysilica at 20℃; for 0.5h; Acetylation;100%
With 3 A molecular sieve; lipase Amono P supported on Celite In various solvent(s) at 25℃; for 5.7h; Acylation;95%
vinyl acetate
108-05-4

vinyl acetate

3-Hydroxybenzyl alcohol
620-24-6

3-Hydroxybenzyl alcohol

3-hydroxybenzyl acetate
142784-72-3

3-hydroxybenzyl acetate

Conditions
ConditionsYield
With Candida cylindracea lipase In hexane for 4h;100%
Y5(OiPr)13O at 20℃; for 18h; Acetylation; transesterification;93%
With Pseudomonas cepacia PS lipase In di-isopropyl ether at 25℃; for 0.5h;
vinyl acetate
108-05-4

vinyl acetate

methyl (2RS,3RS)-2-hydroxy-3-(p-methoxyphenyl)-3-(o-nitrophenylthio)propanoate
30067-00-6, 84056-03-1, 86603-47-6, 125354-93-0, 125354-94-1, 127419-59-4, 131064-04-5, 142926-03-2

methyl (2RS,3RS)-2-hydroxy-3-(p-methoxyphenyl)-3-(o-nitrophenylthio)propanoate

(2R,3R)-2-Acetoxy-3-(4-methoxy-phenyl)-3-(2-nitro-phenylsulfanyl)-propionic acid methyl ester

(2R,3R)-2-Acetoxy-3-(4-methoxy-phenyl)-3-(2-nitro-phenylsulfanyl)-propionic acid methyl ester

Conditions
ConditionsYield
With dmap In tetrahydrofuran at 22℃; for 48h; lipase from Pseudomonas cepacia;100%
vinyl acetate
108-05-4

vinyl acetate

2-(<1,1'-biphenyl>-4-ylmethyl)-1,3-propanediol
152961-72-3

2-(<1,1'-biphenyl>-4-ylmethyl)-1,3-propanediol

(R)-3-Hydroxy-2-(4-phenylbenzyl)propyl acetate
152961-75-6

(R)-3-Hydroxy-2-(4-phenylbenzyl)propyl acetate

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol In di-isopropyl ether; water for 2h; Ambient temperature; lipase PS (Pseudomonas sp.);100%
vinyl acetate
108-05-4

vinyl acetate

benzyl alcohol
100-51-6

benzyl alcohol

A

Benzyl acetate
140-11-4

Benzyl acetate

B

acetaldehyde
75-07-0

acetaldehyde

Conditions
ConditionsYield
With 1,3-dicyclohexylimidazolium-2-thiocarboxylate In tetrahydrofuran at 80℃; for 2h; Inert atmosphere;A 100%
B n/a
With lipase from Pseudomonas Cepacia In benzene at 35℃; other ω-substituted-1-alkanols, var. solvents; kinetic parameters of transesterification;
vinyl acetate
108-05-4

vinyl acetate

benzyl alcohol
100-51-6

benzyl alcohol

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
Y5(OiPr)13O at 20℃; for 42h; Acetylation; transesterification;100%
With dilithium tetra(tert-butyl)zincate In tetrahydrofuran at 25℃; for 1h; Reagent/catalyst; Solvent; Time; Temperature; Inert atmosphere;100%
With P(MeNCH2CH2)3N In tetrahydrofuran for 2h; Ambient temperature;99%
vinyl acetate
108-05-4

vinyl acetate

Geraniol
106-24-1

Geraniol

3,7-dimethyl-2E,6-octadien-1-yl acetate
105-87-3

3,7-dimethyl-2E,6-octadien-1-yl acetate

Conditions
ConditionsYield
With dilithium tetra(tert-butyl)zincate In toluene at 0℃; for 1h; Inert atmosphere;100%
With N,N'-bismesityl-imidazol-2-ylidene In tetrahydrofuran at 20℃; for 1h;99%
1,3-bis(2,4,6-trimethyl-phenyl)imidazol-2-ylidene In tetrahydrofuran at 20℃; for 1h;99%
vinyl acetate
108-05-4

vinyl acetate

(E)-(S)-6-(4-Methoxy-benzyloxy)-2-methyl-hex-2-ene-1,4-diol
208586-48-5

(E)-(S)-6-(4-Methoxy-benzyloxy)-2-methyl-hex-2-ene-1,4-diol

Acetic acid (E)-(S)-4-hydroxy-6-(4-methoxy-benzyloxy)-2-methyl-hex-2-enyl ester
208586-60-1

Acetic acid (E)-(S)-4-hydroxy-6-(4-methoxy-benzyloxy)-2-methyl-hex-2-enyl ester

Conditions
ConditionsYield
In tetrahydrofuran at 0℃; for 24h; PFL enzyme;100%
vinyl acetate
108-05-4

vinyl acetate

(3S,3aS,5aS,8S,9aS,9bS)-8-Hydroxy-3,5a,9-trimethyl-decahydro-naphtho[1,2-b]furan-2-one

(3S,3aS,5aS,8S,9aS,9bS)-8-Hydroxy-3,5a,9-trimethyl-decahydro-naphtho[1,2-b]furan-2-one

A

(11S)-3β,6α-dihydroxy-eudesman-12-oic acid-6-lactone
6089-71-0

(11S)-3β,6α-dihydroxy-eudesman-12-oic acid-6-lactone

B

(11S)-3β-acetoxy-6α-hydroxy-4βH-eudesman-12-oic acid-lactone
74493-56-4

(11S)-3β-acetoxy-6α-hydroxy-4βH-eudesman-12-oic acid-lactone

Conditions
ConditionsYield
With Candida antarctica lipase at 40℃; for 24h; Heating;A 70 mg
B 100%
vinyl acetate
108-05-4

vinyl acetate

2-hydroxymethyl-2,3-dihydrobenzo[1,4]dioxin
3663-82-9

2-hydroxymethyl-2,3-dihydrobenzo[1,4]dioxin

acetic acid 2,3-dihydro-1,4-benzodioxin-2-ylmethyl ester
64179-44-8

acetic acid 2,3-dihydro-1,4-benzodioxin-2-ylmethyl ester

Conditions
ConditionsYield
With N,N'-bismesityl-imidazol-2-ylidene In tetrahydrofuran at 20℃; for 0.25h;100%
1,3-bis(2,4,6-trimethyl-phenyl)imidazol-2-ylidene In tetrahydrofuran at 20℃; for 0.25h;100%
With P(MeNCH2CH2)3N In tetrahydrofuran for 2h; Ambient temperature;99%
vinyl acetate
108-05-4

vinyl acetate

benzyl (1R,2S)-1-hydroxy-2,3-dihydro-1H-inden-2-ylcarbamate

benzyl (1R,2S)-1-hydroxy-2,3-dihydro-1H-inden-2-ylcarbamate

benzyl (1R,2S)-N-(2-acetoxyindan-1-yl)carbamate

benzyl (1R,2S)-N-(2-acetoxyindan-1-yl)carbamate

Conditions
ConditionsYield
With Pseudomonas cepacia lipase In 1,4-dioxane at 30℃; for 120h;100%
vinyl acetate
108-05-4

vinyl acetate

(+/-)-trans-benzyl N-(1-hydroxyindan-2-yl)carbamate

(+/-)-trans-benzyl N-(1-hydroxyindan-2-yl)carbamate

benzyl (1R,2R)-N-(1-acetoxyindan-2-yl)carbamate

benzyl (1R,2R)-N-(1-acetoxyindan-2-yl)carbamate

Conditions
ConditionsYield
With Pseudomonas cepacia lipase In 1,4-dioxane at 30℃; for 48h;100%
vinyl acetate
108-05-4

vinyl acetate

(1R,2S)-(2-hydroxymethylcyclobutyl)methanol
54445-64-6

(1R,2S)-(2-hydroxymethylcyclobutyl)methanol

[(1S,2R)-2-(hydroxymethyl)cyclobutyl]methyl acetate
123809-78-9

[(1S,2R)-2-(hydroxymethyl)cyclobutyl]methyl acetate

Conditions
ConditionsYield
With pseudomonas fluorescens lipase at -2℃; for 13.75h; Acetylation;100%
With Amano lipase AK at -2℃; for 14h; Enzymatic reaction; optical yield given as %ee;99%
vinyl acetate
108-05-4

vinyl acetate

all-cis-5-(tert-butyldimethyl-silanyloxy)-cyclohexane-1,3-diol
187266-42-8, 327189-66-2

all-cis-5-(tert-butyldimethyl-silanyloxy)-cyclohexane-1,3-diol

(1R,3S,5S)-1-acetoxy-3-hydroxy-5-(tert-butyldimethylsilanyloxy)-cyclohexane
327189-67-3

(1R,3S,5S)-1-acetoxy-3-hydroxy-5-(tert-butyldimethylsilanyloxy)-cyclohexane

Conditions
ConditionsYield
With Lipase QL In ethyl acetate at 20℃; for 46h; Acetylation;100%
With Lipase QLM In ethyl acetate at 20℃; Enzymatic reaction;100%
With Lipase QL In ethyl acetate at 22℃; for 46h;99%
With amano lipase SP, from burkholderia cepacia In ethyl acetate at 20℃; Enzymatic reaction;2.356 g
vinyl acetate
108-05-4

vinyl acetate

3-Azido-3-deoxy-4-C-hydroxymethyl-1,2-O-isopropylidene-α-D-erythro-pentofuranose
247025-10-1

3-Azido-3-deoxy-4-C-hydroxymethyl-1,2-O-isopropylidene-α-D-erythro-pentofuranose

3-azido-5-O-acetyl-3-deoxy-4-C-hydroxymethyl-1,2-O-isopropylidene-α-D-erythro-ribofuranose
551934-06-6

3-azido-5-O-acetyl-3-deoxy-4-C-hydroxymethyl-1,2-O-isopropylidene-α-D-erythro-ribofuranose

Conditions
ConditionsYield
With Novozyme-435 In toluene at 25 - 28℃; Enzymatic reaction; regioselective reaction;100%
With Candida antarctica lipase In toluene at 25 - 28℃;98%
vinyl acetate
108-05-4

vinyl acetate

3,6-bis(3,4-dimethoxybenzoyl)-1,2,4,5-tetrazine
534619-54-0

3,6-bis(3,4-dimethoxybenzoyl)-1,2,4,5-tetrazine

3,6-bis(3,4-dimethoxybenzoyl)pyridazine

3,6-bis(3,4-dimethoxybenzoyl)pyridazine

Conditions
ConditionsYield
In toluene at 110℃; for 17h;100%
vinyl acetate
108-05-4

vinyl acetate

benzyl azide
622-79-7

benzyl azide

1-benzyl-1H-[1,2,3]triazole
4368-68-7

1-benzyl-1H-[1,2,3]triazole

Conditions
ConditionsYield
With trimethyl orthoformate at 120℃; for 30h;100%
at 120℃; for 5h; Microwave irradiation; Sealed vial;99%
at 120℃; Sealed tube; Large scale;
(3S,5S,7R,9S,11S,13S)-3,13-Bis-benzyloxymethoxy-pentadecane-1,5,7,9,11,15-hexaol

(3S,5S,7R,9S,11S,13S)-3,13-Bis-benzyloxymethoxy-pentadecane-1,5,7,9,11,15-hexaol

vinyl acetate
108-05-4

vinyl acetate

Acetic acid (3S,5S,7R,9S,11S,13S)-15-acetoxy-3,13-bis-benzyloxymethoxy-5,7,9,11-tetrahydroxy-pentadecyl ester

Acetic acid (3S,5S,7R,9S,11S,13S)-15-acetoxy-3,13-bis-benzyloxymethoxy-5,7,9,11-tetrahydroxy-pentadecyl ester

Conditions
ConditionsYield
With lipase from Candida cylindracea at 25℃; for 6h;100%
(3S,5S,7S)-3-Benzyloxymethoxy-8-[(4S,6R)-6-((S)-2-benzyloxymethoxy-4-hydroxy-butyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-octane-1,5,7-triol

(3S,5S,7S)-3-Benzyloxymethoxy-8-[(4S,6R)-6-((S)-2-benzyloxymethoxy-4-hydroxy-butyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-octane-1,5,7-triol

vinyl acetate
108-05-4

vinyl acetate

Acetic acid (S)-4-[(4R,6S)-6-((2S,4S,6S)-8-acetoxy-6-benzyloxymethoxy-2,4-dihydroxy-octyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-3-benzyloxymethoxy-butyl ester

Acetic acid (S)-4-[(4R,6S)-6-((2S,4S,6S)-8-acetoxy-6-benzyloxymethoxy-2,4-dihydroxy-octyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-3-benzyloxymethoxy-butyl ester

Conditions
ConditionsYield
With lipase from Candida cylindracea at 25℃; for 6h;100%
(3R,5R,7S,9S,11S,13R)-3,13-Bis-benzyloxymethoxy-9-(tert-butyl-dimethyl-silanyloxy)-pentadecane-1,5,7,11,15-pentaol
914803-06-8

(3R,5R,7S,9S,11S,13R)-3,13-Bis-benzyloxymethoxy-9-(tert-butyl-dimethyl-silanyloxy)-pentadecane-1,5,7,11,15-pentaol

vinyl acetate
108-05-4

vinyl acetate

Acetic acid (3R,5S,7S,9S,11R,13R)-15-acetoxy-3,13-bis-benzyloxymethoxy-7-(tert-butyl-dimethyl-silanyloxy)-5,9,11-trihydroxy-pentadecyl ester
914803-10-4

Acetic acid (3R,5S,7S,9S,11R,13R)-15-acetoxy-3,13-bis-benzyloxymethoxy-7-(tert-butyl-dimethyl-silanyloxy)-5,9,11-trihydroxy-pentadecyl ester

Conditions
ConditionsYield
With lipase from Candida cylindracea at 25℃; for 6h;100%
vinyl acetate
108-05-4

vinyl acetate

4-hydroxy-2-sulfolene
6211-59-2

4-hydroxy-2-sulfolene

4-acetoxy-2-thiolene 1,1-dioxide
86597-94-6

4-acetoxy-2-thiolene 1,1-dioxide

Conditions
ConditionsYield
With Novozym 435(R) In acetonitrile at 30℃; for 16h;100%
(4R,5R)-4-acetoxy-7-chloro-5-methoxymethoxy-1-(p-toluenesulfonyl)-2,3,4,5-tetrahydro-1H-1-benzazepine
926035-11-2

(4R,5R)-4-acetoxy-7-chloro-5-methoxymethoxy-1-(p-toluenesulfonyl)-2,3,4,5-tetrahydro-1H-1-benzazepine

vinyl acetate
108-05-4

vinyl acetate

(4R,5R)-7-chloro-4-hydroxy-5-methoxymethoxy-1-(p-toluenesulfonyl)-2,3,4,5-tetrahydro-1H-1-benzazepine
926035-13-4

(4R,5R)-7-chloro-4-hydroxy-5-methoxymethoxy-1-(p-toluenesulfonyl)-2,3,4,5-tetrahydro-1H-1-benzazepine

Conditions
ConditionsYield
Stage #1: (4R,5R)-4-acetoxy-7-chloro-5-methoxymethoxy-1-(p-toluenesulfonyl)-2,3,4,5-tetrahydro-1H-1-benzazepine With sodium hydroxide In ethanol at 20℃; for 0.5h;
Stage #2: vinyl acetate With Lipase QLM In acetonitrile at 65℃; for 1h;
Stage #3: With sodium hydroxide In ethanol at 20℃; for 0.5h; Further stages.;
100%
vinyl acetate
108-05-4

vinyl acetate

3-hexyn-2,5-diol
3031-66-1

3-hexyn-2,5-diol

C8H12O3

C8H12O3

B

Acetic acid (1R,4R)-4-acetoxy-1-methyl-pent-2-ynyl ester
152694-53-6

Acetic acid (1R,4R)-4-acetoxy-1-methyl-pent-2-ynyl ester

C

(2S,5S)-hex-3-yne-2,5-diol
152694-52-5

(2S,5S)-hex-3-yne-2,5-diol

Conditions
ConditionsYield
With lipase AK at 32℃; for 16h; Enzymatic reaction;A n/a
B 100%
C n/a

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