104642-97-9

Upstream product

• 201230-82-2 carbon monoxide 
• 107-05-1 3-chloroprop-1-ene 
• 100-61-8 N-methylaniline 
• 107-93-7 (E)-but-2-enoic acid 
• 625-35-4 trans-chrotonyl chloride 

Downstream Products

• 65844-67-9 dimethyl 3,4-dihydro-3-methyl-5-oxofuran-2,2(3H)-dicarboxylate 
• 1314705-48-0 dimethyl 2-hydroxy-2-{1-methyl-3-[methyl(phenyl)amino]-3-oxopropyl}propanedioate 
• 1314705-66-2 tetramethyl 2-methyl-3-{[methyl(phenyl)amino]carbonyl}buta-1,3-diene-1,1,4,4-tetracarboxylate 
• 1429299-26-2 (R)-N-methyl-N-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butanamide 
• 194096-92-9 (E)-N-methyl-4,N-diphenyl-3-butenamide 
• 138123-49-6 N-Methyl-2-(hydroxyimino)butyranilide 
• 138123-49-6 N-Methyl-2-(hydroxyimino)butyranilide 
• 138123-49-6 N-methyl-2-hydroxyiminobutananilide 
• 130594-41-1 N-Methyl-2-nitrosobutananilide 
• 104643-29-0 C₂₁H₃₁⁽²⁾HN₂O₂ 
• 104643-02-9 N,N-diisopropyl-5-(diisopropylcarbamoyl)-3-methyl-5-heptenamide 
• 104713-93-1 N,N-diisopropyl-N'-phenyl-N',2,2-trimethyl-1,4-cyclopentanedicarboxamide 
• 104643-01-8 N,N-diisopropyl-N'-phenyl-N',2,3-trimethyl-1,4-cyclopentanedicarboxamide 
• 104643-22-3 5-(diisopropylcarbamoyl)-N-phenyl-N,3,4-trimethyl-5-hexenamide 

Relevant academic research and scientific papers

Lewis Acid Enabled Copper-Catalyzed Asymmetric Synthesis of Chiral β-Substituted Amides

Here we report that readily available silyl- and boron-based Lewis acids in combination with chiral copper catalysts are able to overcome the reactivity issues of unactivated enamides, known as the least reactive carboxylic acid derivatives, toward alkyla

PhI(OCOCF3)2-mediated C-C bond formation concomitant with a 1,2-Aryl shift in a metal-free synthesis of 3-arylquinolin-2-ones

The reaction of the readily available N-methyl-N-phenylcinnamamides with phenyliodine bis(trifluoroacetate) (PIFA) in the presence of Lewis acids provides a general and efficient assembly of a variety of 3-arylquinolin-2-one compounds. This novel approach features not only metal-free oxidative C(sp 2)-C(sp2) bond formation but also an exclusive 1,2-aryl migration.

Copper-catalyzed bis(methoxycarbonyl)carbene reactions of α,β-unsaturated carboxamides

The [Cu(acac)2]-catalyzed reactions of α,β- unsaturated carboxamides with dimethyl diazomalonate yielded dihydrofuran derivatives by a 1,5-electrocyclic reaction at C(β), and butadiene derivatives by carbene addition reaction at C(α) (Schemesa

One-pot amide synthesis from allyl or benzyl halides and amines by Pd-catalysed carbonylation

Amides can be prepared from allyl or benzyl halides and primary or secondary amines, using Pd(0) catalyst under CO pressure, in a one-pot synthesis. The reaction proceeds through the acyl palladium halide formation which undergoes an acylic nucleophilic substitution from the amine.