10465-98-2

Usage

Common uses

Crosslinking agent in polymer and resin systems
Curing agent for epoxies and polyurethanes

Applications

Production of adhesives
Coatings
Composite materials

Properties

High thermal stability
Resistance to solvents

Industrial applications

Versatile and valuable additive

Potential uses

Pharmaceutical intermediate
Precursor in the synthesis of functional materials for optoelectronic devices

Upstream product

• 1885-14-9 phenyl chloroformate 

Downstream Products

• 2449-14-1 azodicarboxylic acid diphenyl ester 
• 17696-89-8 1,2-bis(N,N-dimethylcarbamoyl)hydrazine 
• 2449-14-1 Diphenyl azodicarboxylate 
• 255873-61-1 3-[N¹-phenoxycarbonylhydrazido][N²-acetylhydrazino]-N,N-dimethylpropanamide 
• 255873-60-0 3-[N¹-phenoxycarbonylhydrazido][N²-(tert-butoxycarbonyl)hydrazino]-N,N-dimethylpropanamide 
• 1240158-61-5 phenyl N'-(2,2-diphenylethylaminocarbonyl)hydrazinecarboxylate 
• 1240158-45-5 N,N'-bis(2,2-diphenylethyl)-1,2-hydrazidocarboxamide 
• 1240158-46-6 N,N,N’,N’-tetrabenzyl-1,2-hydrazodicarboxamide 
• 1240158-62-6 phenyl N'-(N,N-dibenzylaminocarbonyl)hydrazinecarboxylate 

Relevant academic research and scientific papers

Method of manufacturing Azodicarboxylic acid diester compd. (by machine translation)

PROBLEM TO BE SOLVED: To provide a manufacturing method in which an azodicarboxylate diester compound can be efficiently obtained in a high yield and which is industrially advantageous.SOLUTION: There is provided a manufacturing method for azodicarboxylate diester compound including: a process (a) of obtaining a 1,2-hydrazine dicarboxylate diester compound through reaction between hydrazine and a halocarbonate ester; and a process (b) of obtaining an azodicarboxylate diester compound represented by general formula (2) (where A represents a hydrocarbon or a hydrocarbon which may have an ether bond) by oxidizing the 1,2-hydrazine dicarboxylate diester compound obtained in the process (a), the 1,2-hydrazine dicarboxylate diester compound being neither isolated nor refined.

Synthesis of ring-substituted phenyl hydrazinecarboxylates and study of their protonation in dimethyl sulfoxide solutions

The pKa values of nineteen phenyl hydrazinecarboxylate hydrochlorides R-C6H4OCONHNH2.HCl (R = H, 3-and 4-Cl, 3-and 4-O2N, 4-Me) and their 1-methyl or 2-methyl derivatives were determined by potentiometric titration with tetrabutylammonium hydroxide in DMSO. IR spectra of the hydrazinecarboxylates and their hydrochlorides revealed that the hydrazinecarboxylate protonation occurs at N2. The methods of synthesis of phenyl hydrazinecarboxylate and their N-methyl derivatives were optimized.

Synthesis of a chiral azodicarboxamide containing a bridging binaphthyl moiety: electrophilic amination reactions of achiral ester enolates

A chiral azodicarboxamide 11 containing a bridging binaphthyl group has been prepared by an intermolecular cyclization reaction between the bis(N-methylamine) of 2,2'-dimethyl-1,1'-binaphthyl 6 and N,N'-bis(azidocarbonyl)hydrazine 9, followed by oxidation