104662-03-5Relevant articles and documents
Facile synthesis of α-functionalized vinyl sulfides bearing β-trifluoromethyl group: a highly potential CF3-containing building blocks
Hanamoto, Takeshi,Anno, Ryoko,Yamada, Kenji,Ryu, Kousuke
, p. 3727 - 3730 (2008/02/09)
The β-(trifluoromethyl)vinylsulfides on treatment with n-BuLi/TMEDA were readily lithiated at α-position of the sulfanyl group, and the generated α-lithiovinylsulfides were trapped with a variety of electrophiles to give the corresponding β-trifluoromethy
Claisen rearrangements employing geometrically pure trifluoromethylated allylic Alcohols
Yamazaki, Takashi,Ishikawa, Nobuo
, p. 937 - 943 (2007/10/02)
Claisen and orthoester-Claisen (Johnson-Claisen) rearrangements employing geometrically pure trifluoromethylated allylic alcohols were examined to find that these processes produced rearranged aldehydes or esters in moderate to high yields and in the orth