10468-71-0

Basic information

• Product Name: 1,5-diphenyl-cyclohexene
• Synonyms: 1,5-diphenyl-cyclohexene
• CAS NO: 10468-71-0
• Molecular Weight: 234.341
• Mol File: 10468-71-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,5-diphenyl-cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,5-diphenyl-cyclohexene(10468-71-0)
• EPA Substance Registry System: 1,5-diphenyl-cyclohexene(10468-71-0)

Safety Data

• Hazardous Substances Data: 10468-71-0(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 110-83-8 cyclohexene 
• 190369-93-8 Toluene-4-sulfonic acid 2-phenyl-hex-5-ynyl ester 
• 17799-44-9 3,5-diphenylcyclohex-2-en-1-hydrazone 

Relevant articles and documents

Selective heck arylation of cyclohexene with homogeneous and heterogeneous palladium catalysts

Palladium catalysts containing Pd(II) supported on Al2O 3 and alumina-based mixed oxides, Al2O3- ZrO2, Al2O3-CeO2, and Al 2O3-Fe2O3, are very effective in the Heck coupling of iodobenzene with cyclohexene in DMF solution. The best results, up to 81% of monoarylated products with a selectivity to 4-phenylcyclohexene (3) close to 90% were obtained with KOH as a base. The catalytic activity of palladium supported on aluminabased oxides was compared with that of homogeneous precursors, such as Pd(OAc)2 and PdCl 2(PhCN)2, used in [Bu4N]Br as the reaction medium. Under such conditions homogeneous systems were more selective and produced up to 60% of monoarylated products with a selectivity to 3 close to 60%. Copyright