104699-51-6

Basic information

• Product Name: Benzamide, 4-(2-propenyl)- (9CI)
• Synonyms: Benzamide, 4-(2-propenyl)- (9CI)
• CAS NO: 104699-51-6
• Molecular Formula: C₁₀H₁₁NO
• Molecular Weight: 161.20044
• Product Categories: AMIDE
• Mol File: 104699-51-6.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzamide, 4-(2-propenyl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, 4-(2-propenyl)- (9CI)(104699-51-6)
• EPA Substance Registry System: Benzamide, 4-(2-propenyl)- (9CI)(104699-51-6)

Safety Data

• Hazardous Substances Data: 104699-51-6(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 26, p. 6457, 1985 DOI: 10.1016/S0040-4039(00)99026-9

Upstream product

• 591-87-7 Allyl acetate 
• 698-67-9 p-bromobenzamide 

Relevant articles and documents

Cobalt-catalyzed direct electrochemical cross-coupling between aryl or heteroaryl halides and allylic acetates or carbonates

The electroreduction of a mixture of functionalized aromatic or heteroaromatic bromides or chlorides and allylic compounds such as acetates or carbonates in an electrochemical cell fitted with a sacrificial iron anode affords, in the presence of cobalt halide associated with pyridine as ligand in acetonitrile or DMF, the corresponding coupling product in good yields.

PALLADIUM-CATALYZED CROSS-COUPLING REACTION: DIRECT ALLYLATION OF ARYL BROMIDES WITH ALLYL ACETATE

Various aryl bromides underwent a palladium-catalyzed cross-coupling reaction with allyl acetate in the presence of hexa-n-butylditin to give the allylated products in very high yields.