104710-85-2Relevant academic research and scientific papers
Transition Metal Complexes with Terminal or Bridging Imidato(1-) Ligands. X-Ray Crystal Structures of trans- and 2>*CH2Cl2, Spectroscopic Studies of , and the Nature of the Metal-Nitrog...
Adams, Harry,Bailey, Neil A.,Briggs, Nigel T.,McCleverty, Jon A.,Colquhoun, Howard M.,Williams, David J.
, p. 813 - 820 (2007/10/02)
The reaction of with the thallium(I) salt of succinimide yields the novel succinimidato(1-) complex .The imide-derived ligand is found to behave as a pseudo-halogen in terms of its ?-acceptor and ?-donor properties by 'Graham' analysis of i.r. spectroscopic data.Mononuclear arylpalladium complexes, trans- , and related carbonyl-rhodium and -iridium complexes, trans-, may be synthesised by reaction of the corresponding chloro-complexes with succinimide, phthalimide, or tetrafluorosuccinimide.The structure of trans- has been established crystallographically (Ir-N 2.09 Angstroem).Binuclear arylpalladium complexes containing halide or acetate bridges react with imides in the presence of base to give complexes in which the imidato(1-) ligand adopts a novel bridging co-ordination mode, via nitrogen and one of the carbonyl oxygens.The structure of one complex of this type, 2>*CH2Cl2, has been confirmed crystallographically.
