104729-88-6Relevant articles and documents
Elucidation of the stereochemistry of thiirane formation from a 1λ4,2-dithietane bearing two chiral carbon centers
Kusaka, Shinpei,Kano, Naokazu,Kawashima, Takayuki
, p. 412 - 417 (2010)
A tetracoordinated sulfurane bearing a 1λ4,2-dithietane moiety, whose 3- and 4-positions were chiral carbon centers, was synthesized. Its thermolysis gave the corresponding thiirane as a single diastereomer, whose configuration and stereochemis
Palladium-catalyzed desulfitative hydroarylation of alkynes with sodium sulfinates
Liu, Saiwen,Bai, Yang,Cao, Xiangxiang,Xiao, Fuhong,Deng, Guo-Jun
supporting information, p. 7501 - 7503 (2013/08/23)
A palladium-catalyzed desulfitative hydroarylation of alkynes with aryl sulfinic acid sodium salts is described. The reaction showed good regio- and stereoselectivity, and afforded the hydroarylation products in good yields. Various functional groups were well tolerated under the optimized reaction conditions.