104749-85-1Relevant academic research and scientific papers
Single-Electron-Transfer-Induced C(sp3)-N Couplings via C-C Bond Cleavage of Cycloketoxime Esters
Shi, Zhuangzhi,Wang, Minyan,Zhao, Binlin
, (2019)
A practical single-electron-transfer-induced selective C(sp3)-N coupling of cycloketoximes with anilines via C-C bond cleavage under copper-catalytic and synergetic photoredox/copper-catalytic reaction systems has been uncovered. These two powerful and simple protocols demonstrated excellent selectivity and good functional group compatibility without any base or ligand control. Preliminary mechanistic experiments indicated that a radical-mediated process was involved in these transformations.
Alkaline Sodium Borohydride-Promoted Reductive Alkylation of β-Aminomercurials: Synthesis of 1,5-Functionalized Amines
Barluenga, Jose,Campos, Pedro J.,Lopez-Prado, Joaquin,Asensio, Gregorio
, p. 1125 - 1129 (2007/10/02)
β-Aminoalkyl radicals generated by alkaline sodium borohydride reduction of aminomercurials react with electron-deficient olefins in an one pot procedure.These reactions allow direct synthesis of 5-aminonitriles and 5-aminoesters. 1,5-Diamines and aminoal
