10480-47-4

Basic information

• Product Name: Benzenamine, 4-methoxy-N-[(3-nitrophenyl)methylene]-
• CAS NO: 10480-47-4
• Molecular Formula: C14H12N2O3
• Molecular Weight: 256.261
• Mol File: 10480-47-4.mol
• Article Data: 26

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-methoxy-N-[(3-nitrophenyl)methylene]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-methoxy-N-[(3-nitrophenyl)methylene]-(10480-47-4)
• EPA Substance Registry System: Benzenamine, 4-methoxy-N-[(3-nitrophenyl)methylene]-(10480-47-4)

Safety Data

• Hazardous Substances Data: 10480-47-4(Hazardous Substances Data)

Upstream product

• 619-25-0 3-Nitrobenzyl alcohol 
• 104-94-9 4-methoxy-aniline 
• 99-61-6 3-nitro-benzaldehyde 
• 67-56-1 methanol 
• 62-53-3 aniline 

Downstream Products

• 99-61-6 3-nitro-benzaldehyde 
• 501-58-6 (E)-1,2-bis(4-methoxyphenyl)diazene 
• 38550-54-8 (4-Methoxy-phenylamino)-(3-nitro-phenyl)-acetonitrile 
• 1233714-05-0 1-(4-methoxyphenyl)-4-(3-nitrophenylmethylene)-6-[(Z)-2-(3-nitrophenyl)vinyl]-3H-1,3,5-triazin-2-one 
• 1440008-49-0 ((2S,3S)-1-(4-methoxyphenyl)-2-(3-nitrophenyl)piperidin-3-yl)methanol 
• 1415689-09-6 4-(3-aminophenyl)-3-(2,4-dichlorophenoxy)-1-(4-methoxyphenyl)azetidin-2-one 

Relevant articles and documents

Recyclable hydrotalcite catalysts for alcohol imination via acceptorless dehydrogenation

Here we report that hydrotalcite-like materials (HTs) are active heterogeneous catalysts for alcohol imination, which proceeds through acceptorless alcohol dehydrogenation. The catalytic activity of a series of Mg-Al hydrotalcites doped with Fe3+, Zn2+, Ni2+, Cr3+ and Cu2+ is dependent on their composition, and Fe : Mg : Al HT yields up to 92% imine under mild conditions. Impregnation of Fe : Mg : Al HT with Pd0 resulted in an enhancement of activity for acceptorless dehydrogenation, but a decrease in the isolated yield of imine in a loading-dependent manner. This is attributed to the Pd loading-dependent retention of imine and aldehyde on the catalysts. The substrate scope for alcohol imination and recyclability of the catalysts is discussed.

Spectroscopic and semi-empirical MO study of substituent effects on the intramolecular proton transfer in anils of 2-hydroxybenzaldehydes

Substituent effects in singly and doubly substituted anils of 2- hydroxybenzaldehyde showing strong intramolecular hydrogen bonding are studied on the basis of solution 13C NMR spectroscopic data and semiempirical MO (AM1) calculations of the r

Enantioselective Direct anti-Selective Mannich-type Reactions Catalyzed by 3-Pyrrolidinecarboxylic Acid in the Presence of Potassium Carbonate: Addition of Potassium Carbonate Improves Enantioselectivities

Mannich-type reactions of cyclohexanone and related six-membered-ring ketones with N-p-methoxyphenyl-protected imines of arylaldehydes catalyzed by 3-pyrrolidinecarboxylic acid in the presence of K2CO3 that afford anti-isomers of the Mannich products with

Ru Nanoparticles-Loaded Covalent Organic Framework for Solvent-Free One-Pot Tandem Reactions in Air

Condensation of benzene-1,3,5-tricarbohydrazide with benzene-1,4-dicarboxaldehyde generated a new covalent organic framework, COF-ASB (1), in which the organic units are held together via hydrazone linkage to form porous frameworks. COF-ASB (1) is highly crystalline and displays good chemical and thermal stability and is permanently porous. In addition, 1 can be an ideal support to load Ru nanoparticles (Ru NPs) to generate Ru@COF-ASB (2). The obtained composite material is able to highly promote one-pot tandem synthesis of imine products from benzyl alcohols and corresponding amines under solvent-free conditions in air.