104803-86-3Relevant academic research and scientific papers
Relative Reactivities of Various Sulfides, Selenides and Halides Towards SH2 Attack by Tributyltin Radicals
Beckwith, Athelstan L. J.,Pigou, Paul E.
, p. 77 - 87 (1986)
The order of reactivity towards SH2 attack by tributyltin radicals on various groups X in four different molecular environments (RCO2CH2X, RCH2OCH2X, XCH2CO2Et and RCH2X) has been found by competition experiments to be Br > PhSe > Cl > p-CNC6H4S > PhS > p-MeC6H4S > MeS.The mechanism of the reaction of chloromethyl phenyl sulfide with alkoxides is discussed.
Synthesis of dithioacetals and oxathioacetals with chiral auxiliaries
Zaidi, Javid H.,Naeem, Fazal,Khan, Khalid M.,Iqbal, Rasfaid,Zia-Ullah
, p. 2641 - 2653 (2007/10/03)
One-pot synthesis of dithioacetals as well as an efficient method for oxathioacetal is reported. Additionally, some chiral auxiliaries were used to synthesize enantiomerically pure dithioacetals and oxathioacetals.
