Australian Journal of Chemistry p. 77 - 87 (1986)
Update date:2022-07-30
Topics:
Beckwith, Athelstan L. J.
Pigou, Paul E.
The order of reactivity towards SH2 attack by tributyltin radicals on various groups X in four different molecular environments (RCO2CH2X, RCH2OCH2X, XCH2CO2Et and RCH2X) has been found by competition experiments to be Br > PhSe > Cl > p-CNC6H4S > PhS > p-MeC6H4S > MeS.The mechanism of the reaction of chloromethyl phenyl sulfide with alkoxides is discussed.
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