104816-18-4Relevant academic research and scientific papers
REGIOSELECTIVE REACTIONS OF ENAMINONES WITH ENONES-II. INTRAMOLECULAR REARRANGEMENTS INVOLVING CARBON TO OXYGEN ACYL MIGRATIONS
Kozerski, Lech,Czerwinska, E.,Pobiedzinska, T.
, p. 617 - 621 (2007/10/02)
Intramolecular dynamic behaviour helps in predicting the regioselectivity of reactions in ambident molecules.Thus the enaminones (1) react on the C-2 carbon atom with benzoquinone.Reaction proceeds with an intramolecular acyl shift following formation of the initial reaction complex upon reaction at position C-2 of the enaminone and the quinone.Under certain conditions the reaction is regiospecific and proceeds stereospecifically.
