104828-82-2Relevant academic research and scientific papers
Asymmetric reduction of enantiopure imines with zinc borohydride: Stereoselective synthesis of chiral amines
Cimarelli, Cristina,Palmieri, Gianni
, p. 2555 - 2563 (2007/10/03)
The first application of zinc borohydride in the reduction of enantiopure imines for the stereoselective preparation of both the enantiomers of secondary amines is described. A possible explanation of the stereoselectivity and of the reaction mechanism is
NADH MODELS XXI. STEREOSELECTIVE REDUCTION OF CHIRAL IMINES WITH HANTZSCH ESTER
van Niel, Johannes C.G.,Pandit, Upendra K.
, p. 6005 - 6012 (2007/10/02)
Imines derived from p-substituted acetophenones and (+) R-1-phenylethylamine are reduced by 3,5-diethoxycarbonyl-2,6-dimethyl-1,4-dihydro-pyridine (Hantzsch ester), in acetonitrile, in the presence of magnesium perchlorate, to diastereomeric mixtures of t
