1048375-00-3

Basic information

• Product Name: C₁₅H₁₈SSi
• Synonyms: C₁₅H₁₈SSi
• CAS NO: 1048375-00-3
• Molecular Weight: 258.459
• Mol File: 1048375-00-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₅H₁₈SSi(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₅H₁₈SSi(1048375-00-3)
• EPA Substance Registry System: C₁₅H₁₈SSi(1048375-00-3)

Safety Data

• Hazardous Substances Data: 1048375-00-3(Hazardous Substances Data)

Upstream product

• 766-77-8 Dimethylphenylsilane 
• 106-45-6 para-thiocresol 

Downstream Products

• 1825-58-7 dimethyl(ethoxy)phenylsilane 

Relevant articles and documents

Toward selective functionalisation of oligosilanes: Borane-catalysed dehydrogenative coupling of silanes with thiols

Among established methods for transforming Si-H bonds, carbonyl hydrosilylation and heterodehydrogenative coupling with alcohols catalysed by B(C6F5)3 are shown to provide exceptionally clean routes to the derivatisation of tetra-substituted disilanes such as [Ph2SiH]2, giving no products resulting from Si-Si bond cleavage. Even higher activity is observed for the borane-catalysed dehydrogenative coupling of silanes with alkyl- and arylthiols, the first examples of such Si-S bond formation in the absence of a transition metal catalyst. Clean, quantitative syntheses of a range of thiosilanes are reported, and the lability of the Si-S linkage toward subsequent alcoholysis is investigated. The crystal structure of 2,3-disila-2,2,3,3-tetramethyl-1,4- benzodioxane is presented.