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1825-58-7

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1825-58-7 Usage

Chemical Properties

Colorless or yellowish transparent liquid

Uses

Ethoxydimethylphenylsilane can be used:To functionalize SiO2 nanoparticles by the sol-gel method used in the bilayer coatings on a glass surface.To functionalize the nanosized zeolites applicable in the catalysis.As a substrate in the study of Si-O bond cleavage in the presence of serine hydrolases.

General Description

Ethoxydimethylphenylsilane undergoes trifluoroethanolysis in the presence of substituted acetic acids.{69}

Check Digit Verification of cas no

The CAS Registry Mumber 1825-58-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,8,2 and 5 respectively; the second part has 2 digits, 5 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 1825-58:
(6*1)+(5*8)+(4*2)+(3*5)+(2*5)+(1*8)=87
87 % 10 = 7
So 1825-58-7 is a valid CAS Registry Number.
InChI:InChI=1/C10H16OSi/c1-4-11-12(2,3)10-8-6-5-7-9-10/h5-9H,4H2,1-3H3

1825-58-7 Well-known Company Product Price

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  • Aldrich

  • (41409)  Ethoxydimethylphenylsilane  ≥97.0% (GC)

  • 1825-58-7

  • 41409-5ML

  • 1,440.27CNY

  • Detail

1825-58-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name ethoxy-dimethyl-phenylsilane

1.2 Other means of identification

Product number -
Other names CH3CH2OSiMe2Ph

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1825-58-7 SDS

1825-58-7Relevant articles and documents

ALCOHOLYSIS OF HYDRIDESILANES TO GIVE SILYL ETHERS CATALYZED BY RHODACARBORANES CLOSO-3,3-(Ph3P)2-3-H-3,1,2-RhC2B9H11 AND CLOSO-3,3-(η2,η3-C7H7CH2)-3,1,2-RhC2B9H11

Zakharkin, L. I.,Zhigareva, G. G.

, p. 1284 - 1285 (1992)

Rhodacarboranes closo-3,3-(Ph3P)2-3-H-3,1,2-RhC2B9H11 and closo-(η2,η3-C7H7CH2)-3,1,2-RhC2B9H11 are catalysts for the alcoholysis of hydridesilanes.Closo-(η2,η3-C7H7CH2)-3,1,2-RhC2B9H11 displays greater activity

Cobalt single atoms anchored on nitrogen-doped porous carbon as an efficient catalyst for oxidation of silanes

Yang, Fan,Liu, Zhihui,Liu, Xiaodong,Feng, Andong,Zhang, Bing,Yang, Wang,Li, Yongfeng

, p. 1026 - 1035 (2021/02/09)

The oxidation reactions of organic compounds are important transformations for the fine and bulk chemical industry. However, they usually involve the use of noble metal catalysts and suffer from toxic or environmental issues. Here, an efficient, environmentally friendly, and atomically dispersed Co catalyst (Co-N-C) was preparedviaa simple, porous MgO template and etching method using 1,10-phenanthroline as C and N sources, and CoCl2·6H2O as the metal source. The obtained Co-N-C catalyst exhibits excellent catalytic performance for the oxidation of silanes with 97% isolated yield of organosilanol under mild conditions (room temperature, H2O as an oxidant, 1.8 h), and good stability with 95% isolated yield after nine consecutive reactions. The turnover frequency (TOF) is as high as 381 h?1, exceeding those of most non-noble metal catalysts and some noble metal catalysts. Aberration-corrected high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM), extended X-ray absorption fine structure (EXAFS), and wavelet transform (WT) spectroscopy corroborate the existence of atomically dispersed Co. The coordination numbers of Co affected by the pyrolysis temperature in Co-N-C-700, Co-N-C-800, and Co-N-C-900 are 4.1, 3.6, and 2.2, respectively. Owing to a higher Co-N3content, Co-N-C-800 shows more outstanding catalytic performance than Co-N-C-700 and Co-N-C-800. Moreover, density functional theory (DFT) calculations reveal that the Co-N3structure exhibits more activity compared with Co-N4and Co-N2, which is because the Co atom in Co-N3was bound with both H atom and Si atom, and it induced the longest Si-H bond.

Mechanistic Studies on the Hexadecafluorophthalocyanine–Iron-Catalyzed Wacker-Type Oxidation of Olefins to Ketones**

Grinenko, Vadim,Klau?, Hans-Henning,Kn?lker, Hans-Joachim,Puls, Florian,Seewald, Felix

, p. 16776 - 16787 (2021/11/04)

The hexadecafluorophthalocyanine–iron complex FePcF16 was recently shown to convert olefins into ketones in the presence of stoichiometric amounts of triethylsilane in ethanol at room temperature under an oxygen atmosphere. Herein, we describe an extensive mechanistic investigation for the conversion of 2-vinylnaphthalene into 2-acetylnaphthalene as model reaction. A variety of studies including deuterium- and 18O2-labeling experiments, ESI-MS, and 57Fe M?ssbauer spectroscopy were performed to identify the intermediates involved in the catalytic cycle of the oxidation process. Finally, a detailed and well-supported reaction mechanism for the FePcF16-catalyzed Wacker-type oxidation is proposed.

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