104840-68-8

Upstream product

• 5927-18-4 trimethyl phosphonoacetate 
• 356787-10-5 (2R,3S)-2-(tert-butyldiphenylsilyl)oxy-3,4-epoxy-3-methylbutanal 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 130258-73-0 Methyl 3,4-Isopropylidenedioxy-2-(tert-butyldiphenylsiloxy)butanoate 
• 130258-74-1 4,5-Isopropylidenedioxy-3-(tert-butyldiphenylsiloxy)-2-methylpentan-2-ol 
• 97971-45-4 4,5-Isopropylidenedioxy-3-(tert-butyldiphenylsiloxy)-2-methylpent-1-ene 
• 97971-46-5 3-(tert-Butyldiphenylsiloxy)-4-methyl-but-4-ene-1,2-diol 
• 97971-47-6 2-(tert-Butyldiphenylsiloxy)-3-methyl-but-3-enal 
• 104840-63-3 Methyl 4-(tert-Butyldiphenylsiloxy)-5-methyl-hexa-2(E),5-dienoate 

Downstream Products

• 104855-36-9 Methyl (4R,5S,2'S)-4-(N-Acetylphenylalanyloxy)-5,6-epoxy-5-methyl-hex-2(E)-enoate 
• 104973-50-4 Methyl (4R,5S,2'R)-4-(N-Acetylphenylalanyloxy)-5,6-epoxy-5-methyl-hex-2(E)-enoate 

Relevant academic research and scientific papers

Efficient stereoselective synthesis of a 1-hydroxymethyl-2-methylglycidol derivative

A highly stereoselective synthesis of (2R,3S)-3,4-epoxy-3-methyl-1-(triphenylmethyl)oxybutan-2-ol 3, which is a substructure found in some naturally-occurring bioactive compounds, was achieved starting from commercially available 3-methyl-2-buten-1-ol 4 in three steps, using two applications of the Sharpless asymmetric epoxidation as the key stereochemistry establishing reactions.