1048671-87-9Relevant academic research and scientific papers
Hydroxyl group orientation affects hydrolysis rates of methyl α-septanosides
Markad, Shankar D.,Miller, Shawn M.,Morton, Martha,Peczuh, Mark W.
scheme or table, p. 1209 - 1212 (2010/04/05)
Hydrolysis rates for three related methyl α-septanosides were obtained. The septanosides were synthesized via mCPBA epoxidation and methanolysis of d-mannose, d-galactose, and d-glucose-based oxepines. The rate of hydrolysis correlates with the orientation of hydroxyl groups on the septanose ring in a manner analogous to pyranosides.
Stereoselectivity in the epoxidation of carbohydrate-based oxepines
Markad, Shankar D.,Xia, Shijing,Snyder, Nicole L.,Surana, Bikash,Morton, Martha D.,Hadad, Christopher M.,Peczuh, Mark W.
, p. 6341 - 6354 (2008/12/22)
(Figure Presented) The facial selectivity in the DMDO epoxidation of carbohydrate-based oxepines derived from glucose, galactose, and mannose has been determined by product analysis and density functional theory (DFT, B3LYP/6-31+G**//B3LYP/6-31G*) calcula
