104869-82-1Relevant academic research and scientific papers
Transformations of para-substituted benzylcyclopropanes, allylbenzenes, and diphenylmethanes under nitration with nitric acid in acetic anhydride
Mochalov,Gazzaeva,Fedotov,Archegov,Trofimova,Shabarov,Zefirov
, p. 406 - 416 (2007/10/03)
Electrophilic nitration of benzylcyclopropanes, allylbenzenes, and diphenylmethanes containing ortho, para-orienting substituents in the para position of the benzene ring results mainly in replacement of the cyclopropylmethyl, allyl, or benzyl group, respectively (ipso substitution). The nitration of 4-cyclopropylallylbenzene is not accompanied by nitrodealkylation, and the products are only 2- and 3-nitro-4-cyclopropylallylbenzenes.
Anionic Surfactants Catalysis in the Two-phase Oxidation of Toluene Derivatives with Cerium Ammonium Nitrate. A Facile Synthesis of Some Benzaldehydes
Skarzewski, Jacek,Mlochowski, Jacek
, p. 963 - 967 (2007/10/02)
The catalytic activity of sodium 1-dodecanesulfonate, sodium dodecyl sulfate, disodium 2-dodecyl-1,3-propanediyl disulfate (1) and trisodium 2,2-bis(sulfonatemethyl)tetradecylsulfate(2) was tested in the two-phase oxidation of p-xylene with cerium ammonium nitrate (CAN).Also various tolouene derivatives were oxidized with CAN in the presence of sodium dodecyl sulfate.The observed reaction enhancements are discussed in terms of the micelle-substrate interaction.The catalytic oxidation of some toluene derivatives (3) with a subsequent thermal rearrangement of the oxida tion product offers a simple synthetic route to benzaldehydes 4.
