1048692-97-2

Upstream product

• 1048692-95-0 2-azido-4,4,4,5-tetramethyl-1,3,2-dioxaborolane 
• 110-82-7 cyclohexane 
• 108-91-8 cyclohexylamine 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 
• 76-09-5 2,3-dimethyl-2,3-butane diol 
• 67975-91-1 2-chloro-4,4,5,5,-tetramethyl-1,3,2-dioxaboralane 

Downstream Products

• 108-91-8 cyclohexylamine 
• 1124-53-4 N-cyclohexylacetamide 
• 2211-66-7 N-phenyl(methylidene)cyclohexanamine 

Relevant academic research and scientific papers

Catalyst-free dehydrocoupling of amines, alcohols, and thiols with pinacol borane and 9-borabicyclononane (9-BBN)

Contrary to recent reports, the dehydrocoupling of pinacol borane and 9-borabicyclononane with a variety of amines, alcohols and thiols can be achieved under mild conditions without catalyst. This process involves the formation of Lewis acid-base adducts

Metal-free conversion of methane and cycloalkanes to amines and amides by employing a borylnitrene

(Chemical Equation Presented) C-H insertion: Borylnitrenes, which are generated in situ by photoylsis of azides, convert unactivated alkanes by intermolecular C-H insertion into aminoboranes (see scheme), which in turn can be reacted further to give amines or amides. The boryl group serves two purposes: it converts the nitrene into a highly reactive BN vinylidene analogue, and it is easily cleaved from the product.