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2211-66-7

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2211-66-7 Usage

Synthesis Reference(s)

Tetrahedron, 20, p. 1, 1964 DOI: 10.1016/S0040-4020(01)98389-9Tetrahedron Letters, 19, p. 403, 1978

Check Digit Verification of cas no

The CAS Registry Mumber 2211-66-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,2,1 and 1 respectively; the second part has 2 digits, 6 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 2211-66:
(6*2)+(5*2)+(4*1)+(3*1)+(2*6)+(1*6)=47
47 % 10 = 7
So 2211-66-7 is a valid CAS Registry Number.
InChI:InChI=1/C13H17N/c1-3-7-12(8-4-1)11-14-13-9-5-2-6-10-13/h1,3-4,7-8,11,13H,2,5-6,9-10H2

2211-66-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name N-cyclohexyl-1-phenylmethanimine

1.2 Other means of identification

Product number -
Other names N-benzylidene-1-cyclohexaneamine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2211-66-7 SDS

2211-66-7Relevant articles and documents

Electrochemical dehydrogenation of 1,2,3,4-tetrahydroisoquinoline to 3,4-dihydroisoquinoline

Okimoto, Mitsuhiro,Takahashi, Yukio,Numata, Kaori,Sasaki, Gaku

, p. 371 - 375 (2005)

Dehydrogenation of 1,2,3,4-tetrahydroisoquinoline to 3,4-dihydroisoquinoline was carried out using an electrochemical method in the presence of KI. In this method, the iodide ion presumably played an important role as an electron carrier.

Transient imine as a directing group for the metal-free o-C-H borylation of benzaldehydes

Rej, Supriya,Chatani, Naoto

supporting information, p. 2920 - 2929 (2021/03/01)

Organoboron reagents are important synthetic intermediates and have wide applications in synthetic organic chemistry. The selective borylation strategies that are currently in use largely rely on the use of transition-metal catalysts. Hence, identifying much milder conditions for transition-metal-free borylation would be highly desirable. We herein present a unified strategy for the selective C-H borylation of electron-deficient benzaldehyde derivatives using a simple metal-free approach, utilizing an imine transient directing group. The strategy covers a wide spectrum of reactions and (i) even highly sterically hindered C-H bonds can be borylated smoothly, (ii) despite the presence of other potential directing groups, the reaction selectively occurs at the o-C-H bond of the benzaldehyde moiety, and (iii) natural products appended to benzaldehyde derivatives can also give the appropriate borylated products. Moreover, the efficacy of the protocol was confirmed by the fact that the reaction proceeds even in the presence of a series of external impurities.

Rhodium catalyzed multicomponent dehydrogenative annulation: one-step construction of isoindole derivatives

Cheng, Biao,Lyu, Hairong,Quan, Yangjian,Xie, Zuowei

supporting information, p. 7930 - 7933 (2021/08/17)

A strategy for one-pot synthesis of isoindoles is describedviaa catalytic multicomponent dehydrogenative annulation of diarylimines, vinyl ketones and simple amines. In the presence of a rhodium catalyst and Cu oxidant, four C-H and two N-H bonds are activated along with the formation of one new C-C and two new C-N bonds, leading to a series of isoindole derivatives in good to very high isolated yields.

Redox-Neutral Imination of Alcohol with Azide: A Sustainable Alternative to the Staudinger/Aza-Wittig Reaction

Li, Huaifeng,Lupp, Daniel,Das, Pradip K.,Yang, Li,Gon?alves, Théo P.,Huang, Mei-Hui,El Hajoui, Marwa,Liang, Lan-Chang,Huang, Kuo-Wei

, p. 4071 - 4076 (2021/04/12)

The traditional Staudinger/aza-Wittig reaction represents one of the most powerful tools for imine formation. However, for this multistep procedure, the sacrificial phosphine has to be used, resulting in difficulties in the purification process and waste disposal at the same time. Here, we report a redox-neutral azide-alcohol imination methodology enabled by a base-metal nickel PN3 pincer catalyst. The one-step, waste-free, and high atom-economical features highlight its advantages further. Moreover, mechanistic insight suggests a non-metal-ligand cooperation pathway based on the observation of an intermediate and density functional theory calculations.

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