1048699-48-4Relevant academic research and scientific papers
Arylation of styrenes with aryliron complexes [CpFe(CO)2Ar]
Yasuda, Shigeo,Yorimitsu, Hideki,Oshima, Koichiro
, p. 2634 - 2636 (2010/08/05)
Treatment of aryliron complexes [CpFe(CO)2Ar] with styrenes in boiling xylene affords the corresponding stilbenes. The aryliron complexes, which become active upon heating, serve as arylating agents in the reaction.
Synthesis of aryliron complexes by palladium-catalyzed transmetalation between [CpFe(CO)2I] and aryl Grignard reagents and their chemistry directed toward organic synthesis
Yasuda, Shigeo,Yorimitsu, Hideki,Oshima, Koichiro
, p. 4025 - 4027 (2009/02/06)
Palladium-catalyzed transmetalation between [CpFe-(CO)2I] and aryl Grignard reagents emerges as a new method for the synthesis of [CpFe(CO)2Ar]. The aryliron complexes thus formed are useful arylmetal reagents that become active upon oxidation or UV irradiation.
