CpFe(CO)2(C₆H₄(Bpin)-4)

Base Information

• Chemical Name: CpFe(CO)2(C₆H₄(Bpin)-4)
• CAS No.: 1048699-48-4
• Molecular Formula: C₁₉H₂₁BFeO₄
• Molecular Weight: 380.031
• Mol file: 1048699-48-4.mol

Synonyms:CpFe(CO)2(C₆H₄(Bpin)-4)

Chemical Property of CpFe(CO)2(C₆H₄(Bpin)-4)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of CpFe(CO)2(C₆H₄(Bpin)-4)

There total 2 articles about CpFe(CO)2(C₆H₄(Bpin)-4) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

[CpFe(CO)2C6H4-4-F] (183867-88-1) + bis(pinacol)diborane (73183-34-3) → CpFe(CO)2(C6H4(Bpin)-4) (1048699-48-4)

Guidance literature:

With palladium diacetate; potassium phosphate; XPhos; In 1,4-dioxane; for 5 h at 60°C;

DOI:10.1021/om800560m

Reference yield:

dicarbonylcyclopentadienyliodoiron(II) (12078-28-3,38979-86-1) → CpFe(CO)2(C6H4(Bpin)-4) (1048699-48-4)

Guidance literature:

In not given; treatment of iron compd. with arylmetal deriv. in presence of palladium compd.; Yasuda S., Yorimitsu H., Oshima K., Organometallics 2008, 27, 4025-4027; Asada Y., Yasuda S., Yorimitsu H., Oshima K., Organometallics 2008, 27, 6050-6052;

DOI:10.1021/om1001952

Reference yield: 84.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + CpFe(CO)2(C6H4(Bpin)-4) (1048699-48-4) → C6H5CHCH(C6H4(Bpin)-4) (943858-44-4)

Guidance literature:

In xylene; refluxing mixt. of iron compd., styrene and xylene for 24 h under Ar; cooling to room temp., filtration through silica gel, evapn., chromy. (silica gel, hexane);

DOI:10.1021/om1001952

upstream raw materials:

[CpFe(CO)2C₆H₄-4-F]

bis(pinacol)diborane

dicarbonylcyclopentadienyliodoiron(II)

Downstream raw materials:

CH₂C(CH₃)CH₂C₆H₄BO₂C₂(CH₃)4

1-(3,3-difluoro-2-phenyl-2-propen-1-yl)-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzene

C₆H₅CHCH(C₆H₄(Bpin)-4)