104891-77-2Relevant academic research and scientific papers
HORNER-WITTIG REACTIONS USING DIBENZOPHOSPHOLE OXIDES: STEREOCHEMICALLY CONTROLLED REDUCTION OF KETONES
Elliott, Jason,Warren, Stuart
, p. 645 - 648 (1986)
Reduction of ketones having an α-dibenzophosphole-5-oxide group with NaBH4, L-Selectride, or Superhydride gives threo Horner-Wittig intermediates and hence E-alkenes, while NaBH4/CeCl3 gives erythro intermediates and hence Z-alkenes.
