Tetrahedron Letters p. 645 - 648 (1986)
Update date:2022-07-29
Topics:
Elliott, Jason
Warren, Stuart
Reduction of ketones having an α-dibenzophosphole-5-oxide group with NaBH4, L-Selectride, or Superhydride gives threo Horner-Wittig intermediates and hence E-alkenes, while NaBH4/CeCl3 gives erythro intermediates and hence Z-alkenes.
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