1049017-63-1

Usage

Molecular structure

Complex The molecule has a combination of vinyl, cyclohexene, and aldehyde functional groups.

Aromatic properties

Fragrant The compound has a pleasant aroma, which makes it suitable for use in fragrances and flavors.

Applications

Perfumes, soaps, and cosmetics 1-vinylcyclohex-3-ene carbaldehyde is commonly found in essential oils and is used in the production of various consumer products.

Potential uses

Pharmaceutical and food industries The compound may have applications in these industries due to its unique properties.

Health concerns

Allergen and skin irritant 1-vinylcyclohex-3-ene carbaldehyde can cause allergic reactions and skin irritation, so proper handling precautions should be taken.

Importance

Role in consumer products The compound plays a significant role in the production of various consumer products, both beneficial and potentially harmful.

Upstream product

• 50-00-0 formaldehyd 
• 123-73-9 trans-Crotonaldehyde 
• 106-99-0 buta-1,3-diene 
• 123-73-9 crotonaldehyde 

Downstream Products

• 1049017-68-6 4-vinylcyclohex-1-ene carbaldehyde 
• 16631-66-6 4-Ethylidenecyclohexene 

Relevant academic research and scientific papers

1-VINYLCYCLOHEX-3-ENE CARBALDEHYDE AND 4-VINYLCYCLOHEX-1-ENE CARBALDEHYDE FOR USE IN FLAVOUR AND ORAL CARE COMPOSITION

Provided are oral care compositions comprising a) at least one compound of formula (I) ?wherein R is carbonyl attached at C-1 or C-4; and b) at least one mint flavour, for example, mint oil, menthol, l-carvone, l-limonene or menthone. The compositions possess an enhanced mint flavour character.

NOVEL PROCESS

The present invention relates to a process for the production of formyl cyclohexene derivatives which are suitable as odorants as such or as intermediates for the preparation of further odorants. In particular the present invention relates to a domino-methylenation-Diels-Alder reaction of, α,β-unsaturated aldehydes using formaldehyde in the presence of 1,3-butadienes

Organocatalytic multicomponent α-methylenation/diels-alder reactions: A versatile route to substituted cyclohexenecarbaldehyde derivatives

This article describes the design and optimization of an effective organocatalytic three-componentdomino α-methylenation/Diels-Alder reaction to produce vinyl-substituted cyclohexenecarboxaldehydes in a highly regioselective fashion. In these one-pot transformations, 2-formyl-1,3- butadienes (4) were prepared in situ from α,β-unsaturated aldehydes and formalin and were subsequently trapped with a variety of buta-l,3-dienes. The outcomes of the reactions were dependent on the electronic properties of the dienes. 1-Vinylcyclohexenecarbaldehydes 6 were formed by use of acyclic electron-rich dienes, while the initially formed cycloadducts of 4 with cyclopentadiene underwent Cope rearrangements, leading to the formation of tetrahydro-3H-indene-5-carbaldehyde compounds 7. The mechanisms involved in these reactions were deduced from experimental findings. Furthermore, the method was also extended to one-pot domino methylenation/ Diels-Alder reactions of dihydrofurans and dihydropyrans to yield spirocyclic lactols 22. In these reactions, the unstable intermediate hydroxyethyl and hydroxypropyl acroleins behaved as dienophiles, undergoing cycloaddition reactions with dienes with good yields and selectivities. The wide variety of functionalized 1-vinylcyclohex-3-enecarbaldehydes 6, 4-vinylcyclohex-l-enecarbaldehydes 7, and spiro lactols 22 generated through the use of these organocatalytic domino processes as a diversityoriented synthesis provided useful intermediates for the construction of novel odorants.