10491-63-1Relevant academic research and scientific papers
Tris(trimethylsilyl)silane as mediator in the radical-based allylation reactions of allyl and 2-functionalized allyl phenyl sulfones
Chatgilialoglu, Chryssostomos,Alberti, Angelo,Ballestri, Marco,Macciantelli, Dante,Curran, Dennis P.
, p. 6391 - 6394 (1996)
Radical allylations with 2-functionalized allyl phenyl sulfones have been performed by using tris(trimethylsilyl)silane as radical mediator. Yields varied from moderate to good depending on the nature of the starting materials. EPR studies on the alkyl radical adducts of allyl sulfones have been performed and conformational information has been obtained for the tert-butyl and tetrahydrofuranyl adducts of 2-carboxy allyl tris(trimethylsilyl)silane.
