104994-63-0

Upstream product

• 75251-60-4 1L-1,7-Anhydro-1-C-hydroxymethyl-3,4:5,6-di-O-isopropyliden-2-O-methyl-chiro-inosit 
• 104976-16-1 1L-1,3,4-Tri-O-benzyl-1-C-benzyloxymethyl-5,6-O-isopropyliden-2-O-methyl-chiro-inosit 
• 100-39-0 benzyl bromide 
• 358-23-6 trifluoromethylsulfonic anhydride 
• 104976-17-2 1L-1,3,4-Tri-O-benzyl-1-C-benzyloxymethyl-2-O-methyl-chiro-inosit 

Downstream Products

• 104976-19-4 1L-(1,2,4/3)-1,3,4-Tri-O-benzyl-1-C-benzyloxymethyl-2-O-methyl-5-O-<(trifluormethyl)sulfonyl>-5-cyclohexen-1,2,3,4,5-pentol 
• 104976-20-7 1D-(1,2,4/3)-5-C-Benzyloxymethyl-2,3-di-O-benzyl-4-O-methyl-5-cyclohexen-1,2,3,4-tetrol 
• 104976-21-8 1L-(1,2,4,5/3)-1-C-Benzyloxymethyl-1,3,4-tri-O-benzyl-2-O-methyl-1,2,3,4,5-cyclohexanpentol 
• 104976-18-3 1L-(1,2,4/3)-1,3,4-Tri-O-benzyl-1-C-benzyloxymethyl-2-O-methyl-5-cyclohexen-1,2,3,4-tetrol 

Relevant academic research and scientific papers

Cyclitol Reactions, XIV.- Synthesis of Building Units of Pseudo-α-D-glucopyranose and of Valiol

Regio- and stereoselective addition of ethyl 2-lithio-1,3-dithiolane-2-carboxylate to the enone 2, prepared from quebrachitol, yields the product 3 with an equatorial side-chain.Reduction of 3 leads to 7, which can be transformed into the hydroxymethyl de