105-85-1 Usage
Chemical Properties
Different sources of media describe the Chemical Properties of 105-85-1 differently. You can refer to the following data:
1. Colorless liquid; floral odor.
One volume dissolves in three volumes 80% alcohol; soluble in most oils. Combustible.
2. Citronellyl Formate is a liquid with a
strongly fruity, rose-like odor, which is suitable for fresh top notes in rose and lily
of the valley fragrances.
3. Citronellyl formate has a strong, fruity, rose-like odor with a sweet, fruity taste.
Occurrence
Reported present in geranium essential oil and in the oils of Rosa borbonica, Cupressus lusitanica. Reported
found in mandarin, satsuma and kumquat peel oil, laurel (Laurus nobilis L.), lovage root, black currant buds, basil and honey.
Uses
Flavoring.
Preparation
By direct esterification of citronellol with formic acid.
Taste threshold values
Taste characteristics at 20 ppm: floral, waxy, fruity, citrus and tangerine.
Flammability and Explosibility
Notclassified
Safety Profile
Mildly toxic by
ingestion. A human skin irritant.
Combustible liquid. When heated to
decomposition it emits acrid smoke and
irritating fumes. See also ESTERS and
FORMIC ACID.
Check Digit Verification of cas no
The CAS Registry Mumber 105-85-1 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,0 and 5 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 105-85:
(5*1)+(4*0)+(3*5)+(2*8)+(1*5)=41
41 % 10 = 1
So 105-85-1 is a valid CAS Registry Number.
InChI:InChI=1/C11H20O2/c1-10(2)5-4-6-11(3)7-8-13-9-12/h5,9,11H,4,6-8H2,1-3H3/t11-/m0/s1
105-85-1Relevant articles and documents
Reptilian chemistry: volatile compounds from paracloacal glands of the American crocodile (Crocodylus acutus).
Garcia-Rubio, Silvina,Attygalle, Athula B,Weldon, Paul J,Meinwald, Jerrold
, p. 769 - 781 (2002)
The secretion of the paracloacal glands of the American crocodile (Crocodylus acutus) contains over 80 lipophilic compounds, including saturated and unsaturated long-chain alcohols along with their formic, acetic, and butyric acid esters, and several isoprenoids. Most of these compounds were identified on the basis of mass spectra, obtained by GC-MS. In addition, identification of the major components was supported by infrared spectra obtained by GC-FTIR. Major differences are indicated in the composition of the paracloacal gland secretion of C. acutus and that of another crocodylid, the African dwarf crocodile (Osteolaemus tetraspis).
Formyloxyacetoxyphenylmethane and 1,1-diacylals as versatile O-formylating and O-acylating reagents for alcohols
Chapman, Robert S.L.,Francis, Molly,Lawrence, Ruth,Tibbetts, Joshua D.,Bull, Steven D.
, p. 6442 - 6452 (2018/10/02)
Formyloxyacetoxyphenylmethane, symmetric 1,1-diacylals and mixed 1-pivaloxy-1-acyloxy-1-phenylmethanes have been used as moisture stable O-formylating and O-acylating reagents for primary and secondary alcohols, allylic alcohols and phenols under solvent/catalyst free conditions to afford their corresponding esters in good yield.
