105013-74-9

Usage

InChI:InChI=1/C15H24O2/c1-13(2)11-6-8-14(3)7-4-5-12(10-16)15(14,9-11)17-13/h5,11,16H,4,6-10H2,1-3H3/t11-,14+,15+/m1/s1

Upstream product

• 849949-32-2 10-epieudesm-4-ene-3,11-diols 
• 5956-12-7 5,11-oxy-5β,10α-eudesm-3-ene 
• 141422-50-6 (+)-12-Oxo-α-agarofuran 

Downstream Products

• 105013-72-7 (-)-Baimuxinol 
• 122798-42-9 (-)-Isobaimuxinol 

Relevant academic research and scientific papers

Stereoselective synthesis of dehydrobaimuxinol

A stereoselective synthesis of dehydrobaimuxinol (1) is reported by employing an allylic oxidation as a key step.

Total Synthesis of ( - )-Baimuxifuranic Acid

The first total synthesis of ( - )-baimuxifuranic acid (1) starting from ( - )-carvone is described: in our studies a surprising allylic oxidation was found in the oxidation of an α,β-unsaturated aldehyde 5 with silver oxide.

Improved synthesis of (+)-dehydrobaimuximol, (-)-isobaimuxinol and (-)-baimuxinol from (-)-carvone

An improved synthesis of (+)-dehydrobaimuxinol (1), (-)-isobaimuxinol (2) and (-)-baimuxinol (3) (2-hydroxymethyl-6,10,10-trimethyl-11-oxatricyclo[7.2.1.01,6]dodeca nes) has been described starting from (-)-carvone (p-mentha-6,8-dien-2-one) (4). The key step is the regiospecific allylic oxidation of α-agarofuran (7) by selenium(IV) oxide.