105065-55-2Relevant articles and documents
Stereoselective Synthesis of Alcohols, XXXI. - Stereoselective C-C Bond Formation Using Chiral Z-Pentenylboronates
Hoffmann, Reinhard W.,Ditrich, Klaus,Koester, Gerhard,Stuermer, Rainer
, p. 1783 - 1790 (2007/10/02)
Using 1,2-dicyclohexyl-1,2-ethanediol as chiral auxiliary, the enantiomerically pure Z-pentenylboronate 9c was obtained.Its addition to benzaldehyde proceeded with complete transfer of chirality to give the syn-E-homoallyl alcohol 11.The ability of the re