6524-17-0

Upstream product

• 60-29-7 diethyl ether 
• 590-15-8 trans-2-propenyl bromide 
• 1522-03-8 tetra-cis-propenyl stannane 
• 591-51-5 phenyllithium 
• 1522-03-8 tetra-trans-propenyl stannane 

Downstream Products

• 6052-56-8 1,1-diphenyl-2-buten-1-ol 
• 52755-38-1 (Z)-1-phenyl-but-2-en-1-ol 
• 120850-93-3 (4R,5R)-4,5-dicyclohexyl-2-(Z-propenyl)-1,3,2-dioxaborolane 
• 120788-78-5 (4R,5R)-2-{(2Z)-2-butenyl}-4,5-dicyclohexyl-1,3,2-dioxaborolane 
• 6052-56-8 1,1-diphenyl-2-buten-1-ol 
• 52755-39-2 (2E)-1-phenylbut-2-en-1-ol 
• 1569-50-2 3-penten-2-ol 
• 4683-67-4 (E)-1,2,3,4,5-pentafluoro-6-(prop-1-en-1-yl)benzene 
• 1554-48-9 1,2,4,5-tetrafluoro-3,6-bis[(E)-prop-1-en-1-yl]benzene 
• 108897-21-8 1-(1-phenyl-but-2ξ-enyl)-pyrrolidine 
• 1554-48-9 1,2,4,5-Tetrafluor-3.6-bis--benzol 
• 19140-58-0 1,2,3,4,5-pentafluoro-6-(prop-1-en-1-yl)benzene 
• 41905-69-5 ((Z)-1-Methoxy-but-1-enyl)-benzene 
• 2924-25-6 1-(1-propenyl)-3-(trifluoromethyl)benzene 

Relevant academic research and scientific papers

Ligand-Free Iron-Catalyzed Carbon(sp2)-Carbon(sp2) Cross-Coupling of Alkenyllithium with Vinyl Halides

An efficient ligand-free iron-catalyzed cross-coupling reaction involving alkenyllithium and vinyl iodides was developed to form diene species in moderate to good yields. This new iron-catalyzed cross-coupling reaction provides a mild, inexpensive, and environmentally friendly avenue toward synthesis of diversified diene derivatives.

Palladium-Catalyzed [3+3] Annulation of Vinyl Chromium(0) Carbene Complexes through Carbene Migratory Insertion/Tsuji–Trost Reaction

Vinyl chromium(0) Fischer carbene complexes were employed as the source of π-allylic palladium species for catalytic [3+3] annulation under palladium catalysis. Mechanistically, this transformation is proposed to involve carbene migratory insertion and intramolecular Tsuji–Trost reaction as the key steps. Substituted six-membered heterocyclic flavonones and quinolines are obtained, depending on the nucleophilic functional group on the coupling partners.