105131-69-9Relevant academic research and scientific papers
?-Alkynyl Complexes of Manganese(I) as η2-Bonding Ligands for Group 1B Metal-Ligand Fragments. X-Ray Crystal Structure of t)2(CO)6(dppe)2>PF6*0.5CH2Cl2
Carriedo, Gabino A.,Miguel, Daniel,Riera, Victor,Solans, X.
, p. 2867 - 2874 (2007/10/02)
Several compounds of the types (n=1; M=Cu, Ag, or Au); R=CH2OMe, But, or Ph; dppe=Ph2PCH2CH2PPh2> and have been prepared from the alkynyl complexes fac- and the appropriate reagents to generate the metal-ligand fragments Ml.The salt has been characterized by X-ray diffraction. several equilibri in solution involving the cationic species with free ?-alkynyl complex and P(C6H4Me-2)3 have been observed and their reactions with Cl(1-) have been examined.
