105140-27-0

Basic information

• Product Name: (2S,4S,5R)-2-((S)-2-Methoxycarbonyl-1-methyl-ethyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester
• CAS NO: 105140-27-0
• Molecular Weight: 397.471
• Mol File: 105140-27-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2S,4S,5R)-2-((S)-2-Methoxycarbonyl-1-methyl-ethyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,4S,5R)-2-((S)-2-Methoxycarbonyl-1-methyl-ethyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester(105140-27-0)
• EPA Substance Registry System: (2S,4S,5R)-2-((S)-2-Methoxycarbonyl-1-methyl-ethyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester(105140-27-0)

Safety Data

• Hazardous Substances Data: 105140-27-0(Hazardous Substances Data)

Upstream product

• 105140-28-1 (2S,4S,5R)-2-(1-Methoxycarbonylmethyl-pentyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester 
• 105140-32-7 (2S,4S,5R)-2-(1-Methoxycarbonylmethyl-butyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester 
• 105140-29-2 (2S,4S,5R)-2-(1-Methoxycarbonylmethyl-propyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester 
• 105140-27-0 (2S,4S,5R)-2-(2-Methoxycarbonyl-1-methyl-ethyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester 
• 104863-92-5 (1R,2S)-1-phenyl-2-benzyloxycarbonylamino-1-propanol 
• 32815-00-2 monofumaraldehyde dimethylacetal monomethylester 
• 105226-55-9 (2S,4S,5R)-2-((E)-2-Methoxycarbonyl-vinyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester 
• 917-54-4 methyllithium 
• 186581-53-3 diazomethane 
• 120810-95-9 (2S,4S,5R)-2-((S)-2-Carboxy-1-methyl-ethyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester 

Downstream Products

• 104863-92-5 (1R,2S)-1-phenyl-2-benzyloxycarbonylamino-1-propanol 
• 70423-38-0 (S)-2-methyl-1,4-butandiol 
• 105226-55-9 (2S,4S,5R)-2-((E)-2-Methoxycarbonyl-vinyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester 
• 113323-06-1 (2S,4S,5R)-4-Methyl-5-phenyl-2-vinyl-oxazolidine-3-carboxylic acid benzyl ester 
• 113323-11-8 [(1S,2R)-2-((E)-1-Methoxy-but-2-enyloxy)-1-methyl-2-phenyl-ethyl]-carbamic acid benzyl ester 
• 105140-30-5 (2S,4S,5R)-2-((R)-1-Methoxycarbonylmethyl-allyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester 
• 113323-12-9 (E)-4-((1R,2S)-2-Benzyloxycarbonylamino-1-phenyl-propoxy)-4-methoxy-but-2-enoic acid methyl ester 
• 113427-46-6 (2R,4S,5R)-2-((E)-2-Methoxycarbonyl-vinyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester 
• 113323-15-2 (2S,4S,5R)-2-((R)-1-Methoxycarbonylmethyl-but-3-enyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester 
• 105140-31-6 (2S,4S,5R)-2-((S)-1-Methoxycarbonylmethyl-but-3-enyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester 
• 105140-29-2 (2S,4S,5R)-2-((S)-1-Methoxycarbonylmethyl-propyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester 
• 105140-32-7 (2S,4S,5R)-2-((S)-1-Methoxycarbonylmethyl-butyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester 
• 105140-28-1 (2S,4S,5R)-2-((S)-1-Methoxycarbonylmethyl-pentyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester 
• 105226-56-0 methyl (3S)-3-methyl-4-oxobutanoate 

Relevant articles and documents

Norephedrine-Derived 2-Alkenyloxazolidines: Stereochemistry of Cyclization and Allylic Stereocenter Directed Asymmetric Conjugate Addition

A study on the stereochemistry of the acid-catalyzed cyclization between N-protected norephedrine and α,β-unsaturated dimethyl acetals to give the title compounds is reported.Such heterocycles, on the basis of their different formation and reactivity beha

Allylic Stereocenter Directed Asymmetric Conjugate Addition. Enantioselective Synthesis of 3-Alkylsuccinaldehydic Acid Methyl Esters

Cuprate reagents add to ester 2 with excellent ?-face selectivity (>=95:5) and furnish the title compounds in high enantiomeric excess after removal of the chiral auxiliary.