105147-38-4

Basic information

• Product Name: 2-[4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-phenoxy]-[1,4]benzoquinone
• Synonyms: 2-[4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-phenoxy]-[1,4]benzoquinone
• CAS NO: 105147-38-4
• Molecular Weight: 778.91
• Mol File: 105147-38-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-[4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-phenoxy]-[1,4]benzoquinone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-phenoxy]-[1,4]benzoquinone(105147-38-4)
• EPA Substance Registry System: 2-[4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-phenoxy]-[1,4]benzoquinone(105147-38-4)

Safety Data

• Hazardous Substances Data: 105147-38-4(Hazardous Substances Data)

Upstream product

• 105147-39-5 2-[4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-phenoxy]-benzene-1,4-diol 
• 106-51-4 p-benzoquinone 
• 57412-08-5 5-(4-hydroxyphenyl)-10,15,20-tris(4-methylphenyl)porphyrin 
• 57412-08-5 5-(4-hydroxyphenyl)-10,15,20-tri(p-tolyl)porphyrin 

Downstream Products

• 105147-39-5 2-[4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-phenoxy]-benzene-1,4-diol 

Relevant articles and documents

An Efficient Photochemical Synthesis of Conformationally Restricted Quinone-substituted Porphyrins

Quinone-substituted porphyrins were synthesized by the self-photosensitized reaction of porphyrins including phenol groups; intramolecular fluorescence quenching was inefficient in the conformationally restricted systems.

CIDNP STUDY ON PORPHYRIN-PHOTOSENSITIZED REACTIONS WITH PHENOL AND QUINONE; DIMERIZATION OF 4-METHOXYPHENOL AND CROSS COUPLING OF BENZOQUINONE TO PORPHYRINS COVALENTLY LINKED WITH PHENOL GROUP

Photoreactions of porphyrin (TPP) with phenol and/or quinone in non-polar benzene solution were studied mainly by the CIDNP technique.In the photoreaction of TPP with 4-methoxyphenol (1), CIDNP effects due to TPP.- and 1.+ were observed, while the generation of considerable amounts of free 4-methoxyphenoxyl radical was indicated by ESR and CIDNP in the three-component system involving TPP, 1, and p-benzoquinone (Q).Based on these results, two new photoreactions leading to permanent products were developed: (1) photosensitized dimerization of 1 and (2) photo-induced cross coupling of Q to porphyrins covalently linked with phenol group.The unique role of phenol in the photo-induced electron transfer reaction of TPP and Q in a non-polar solvent was discussed in terms of its dual function as both the proton and electron donor.