105147-59-9

Upstream product

• 105147-56-6 Propionic acid (1R,2R)-1-((R)-3-benzyloxy-1-iodomethyl-propyl)-2-methyl-3-trimethylsilanyl-but-3-enyl ester 
• 105147-69-1 BHT ester of 4-benzyloxybutanoic acid 
• 105147-57-7 (5R,6S)-5-(2-Benzyloxy-ethyl)-3-methyl-6-((R)-1-methyl-2-trimethylsilanyl-allyl)-tetrahydro-pyran-2-one 
• 105147-55-5 (2S,3S,4R)-2-(2-Benzyloxy-ethyl)-4-methyl-5-trimethylsilanyl-hex-5-ene-1,3-diol 
• 95201-30-2 (R)-2-Methyl-3-trimethylsilylbut-3-enal 
• 105226-85-5 (2S,4R,5S,6R)-4-(2-Benzyloxy-ethyl)-2,6-dimethyl-7-trimethylsilanyl-oct-7-ene-1,5-diol 

Downstream Products

• 83005-67-8 (R)-2-[(2S,3R,5R)-3-(2-Benzyloxy-ethyl)-5-methyl-6-oxo-tetrahydro-pyran-2-yl]-propionaldehyde 
• 105147-63-5 (4R,5S,6S,7R,9R)-7-(2-Benzyloxy-ethyl)-10-(tert-butyl-dimethyl-silanyloxy)-5,9-dimethyl-2-trimethylsilanyl-6-trimethylsilanyloxy-dec-1-en-4-ol 
• 105147-61-3 (2R,3S,4R,6R)-4-(2-Benzyloxy-ethyl)-7-(tert-butyl-dimethyl-silanyloxy)-6-methyl-2-((R)-2-trimethylsilanyl-oxiranyl)-heptan-3-ol 
• 105147-60-2 (3R,4S,5R,7R)-5-(2-Benzyloxy-ethyl)-8-(tert-butyl-dimethyl-silanyloxy)-3,7-dimethyl-2-trimethylsilanyl-oct-1-en-4-ol 

Relevant academic research and scientific papers

STEREOCONTROLLED SYNTHESIS OF SEGMENTS FOR THE SYNTHESIS OF TYLONOLIDE BY USING A RELATIVE 1,2-ASYMMETRIC INDUCTION

Two precursors corresponding to the C(1)-C(9) and C(13)-C(17) portions of tylonolide were synthesized in which all the chiral centers were induced correctly from the only one stereocenter existing in 2-methyl-3-trimethylsilylbut-3-enal and 2-benzyloxy-met