83005-67-8

Upstream product

• 83025-06-3 (3R,5R,6S)-5-(2-Benzyloxy-ethyl)-6-[(1R,3S)-3-(tert-butyl-dimethyl-silanyloxy)-3-cyclohexyl-1-methyl-2-oxo-propyl]-3-methyl-tetrahydro-pyran-2-one 
• 105147-59-9 (2R,4R,5S,6R)-4-(2-Benzyloxy-ethyl)-2,6-dimethyl-7-trimethylsilanyl-oct-7-ene-1,5-diol 
• 10385-30-5 4-(benzyloxy)butanoic acid 
• 83005-57-6 2-(2-Benzyloxy-ethyl)-4-methyl-pent-4-enal 
• 83005-56-5 2-(2-Benzyloxy-ethyl)-4-methyl-pent-4-en-1-ol 
• 83005-55-4 2-(2-Benzyloxy-ethyl)-4-methyl-pent-4-enoic acid 
• 83005-63-4 (1S,3R,4S,5R,7R)-5-(2-Benzyloxy-ethyl)-1-(tert-butyl-dimethyl-silanyloxy)-1-cyclohexyl-4,8-dihydroxy-3,7-dimethyl-octan-2-one 
• 83005-61-2 (1S,3R,4S,5R)-5-(2-Benzyloxy-ethyl)-1-(tert-butyl-dimethyl-silanyloxy)-1-cyclohexyl-3,7-dimethyl-4-triethylsilanyloxy-oct-7-en-2-one 
• 83058-26-8 (1S,3R,4S,5R)-5-(2-Benzyloxy-ethyl)-1-(tert-butyl-dimethyl-silanyloxy)-1-cyclohexyl-4-hydroxy-3,7-dimethyl-oct-7-en-2-one 
• 83005-62-3 (1S,3R,4S,5R,7R)-5-(2-Benzyloxy-ethyl)-1-(tert-butyl-dimethyl-silanyloxy)-1-cyclohexyl-8-hydroxy-3,7-dimethyl-4-triethylsilanyloxy-octan-2-one 
• 105147-55-5 (2S,3S,4R)-2-(2-Benzyloxy-ethyl)-4-methyl-5-trimethylsilanyl-hex-5-ene-1,3-diol 
• 105147-57-7 (5R,6S)-5-(2-Benzyloxy-ethyl)-3-methyl-6-((R)-1-methyl-2-trimethylsilanyl-allyl)-tetrahydro-pyran-2-one 
• 105147-56-6 Propionic acid (1R,2R)-1-((R)-3-benzyloxy-1-iodomethyl-propyl)-2-methyl-3-trimethylsilanyl-but-3-enyl ester 
• 105147-69-1 BHT ester of 4-benzyloxybutanoic acid 

Relevant academic research and scientific papers

STEREOCONTROLLED SYNTHESIS OF SEGMENTS FOR THE SYNTHESIS OF TYLONOLIDE BY USING A RELATIVE 1,2-ASYMMETRIC INDUCTION

Two precursors corresponding to the C(1)-C(9) and C(13)-C(17) portions of tylonolide were synthesized in which all the chiral centers were induced correctly from the only one stereocenter existing in 2-methyl-3-trimethylsilylbut-3-enal and 2-benzyloxy-met