105147-87-3Relevant academic research and scientific papers
Coenzyme Models. 47. Synthesis and Reactivity Studies of Novel Flavinophanes and 5-Deazaflavinophanes: Correlation between Flavin Reactivity and Ring Strain
Shinkai, Seiji,Kawase, Akito,Yamaguchi, Toshiro,Manabe, Osamu,Wada, Yoshikazu,et al.
, p. 4928 - 4935 (2007/10/02)
New flavinophanes Fl(n) and 5-deazaflavinophanes dFl(n) were synthesized in which N(3) and O(2') in the 10-(2-hydroxyphenyl) group were linked by a -(CH2)n- chain (n = 6, 7, 8, 10, and 12).In the (1)H NMR spectra the chemical shift of 9-H in the isoalloxa
SYNTHESIS OF NEW DEAZAFLAVINS WITH PLANAR CHIRALITY. REDOX-INDUCED "ROPE-SKIPPING" RACEMIZATION
Shinkai, Seiji,Yamaguchi, Toshiro,Nakao, Hideki,Manabe, Osamu
, p. 1611 - 1614 (2007/10/02)
New 5-deazaflavins with planar chirality (dF1(n)) were synthesized in which N(3) and O(2'α) in the 10-(2'-hydroxy)phenyl group were linked by a -(CH2)- chain (n=8,10). (+)-dF1(n=8) showed a large chiral discrimination in fluorescence quenching
