105154-79-8

Basic information

• Product Name: [(CH3C(CH2PPh2)3)Rh(η(2)-C2H4)(H)]
• Synonyms: [(CH3C(CH2PPh2)3)Rh(η(2)-C2H4)(H)]
• CAS NO: 105154-79-8
• Molecular Weight: 756.649
• Mol File: 105154-79-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: [(CH3C(CH2PPh2)3)Rh(η(2)-C2H4)(H)](CAS DataBase Reference)
• NIST Chemistry Reference: [(CH3C(CH2PPh2)3)Rh(η(2)-C2H4)(H)](105154-79-8)
• EPA Substance Registry System: [(CH3C(CH2PPh2)3)Rh(η(2)-C2H4)(H)](105154-79-8)

Safety Data

• Hazardous Substances Data: 105154-79-8(Hazardous Substances Data)

Upstream product

• 100333-94-6 RhH₃(triphos) 
• 74-85-1 ethene 
• 127332-18-7 RhCl(⁽¹³⁾C₂H₄){CH₃C(CH₂P(C₆H₅)2)3} 
• 15523-24-7 sodium tetraethylborate 
• 105139-41-1 (triphos)RhCl(C₂H₄) 
• 925-90-6 ethylmagnesium bromide 

Downstream Products

• 100333-94-6 RhH₃(triphos) 

Relevant articles and documents

Rhodium Complexes with the Tripodal Triphosphine MeC(CH2PPh2)3 as Highly Reactive Systems for Hydrogenation and Hydroformylation of Alkenes

The (triphos)Rh fragment is able to form strong bonds with several reactive species (hydride, alkyl, carbon monoxide, alkenes), some reactions of which are highly specific; preliminary results on the hydrogenation and hydroformylation of hex-1-ene using (triphos)RhH(C2H4) as catalyst precursor are discussed.

Tripodal polyphosphine ligands in homogeneous catalysis. 1. Hydrogenation and hydroformylation of alkynes and alkenes assisted by organorhodium complexes with MeC(CH2PPh2)3

This paper describes the synthesis and the chemical-physical properties of a number of new mononuclear organorhodium complexes of triphos. A detailed study on the hydrogenation reactions of various alkenes and alkynes and on the hydroformylation reactions of alkenes has been carried out. Also, the study compares and contrasts the catalytic activity of complexes containing participative ligands with that of (i) related mononuclear species containing non-participative ligands, and (ii) related dirhodium complexes.