1051925-24-6Relevant articles and documents
Synthesis of N-allylideneamines and their use for the double nucleophilic addition of ketene silyl (thio)acetals and trimethylsilyl cyanide
Mizota, Isao,Matsuda, Yuri,Hachiya, Iwao,Shimizu, Makoto
, p. 3977 - 3980 (2008)
(Chemical Equation Presented) N-Allylideneamines 1a,b were prepared from acrolein and diphenylethyl or trityl amine in the presence of Ti(OEt) 4. Double nucleophilic addition of various ketene silyl (thio)acetals and trimethylsilyl cyanide to t
Conjugated imines and iminium salts as versatile acceptors of nucleophiles
Shimizu, Makoto,Hachiya, Iwao,Mizota, Isao
scheme or table, p. 874 - 889 (2009/07/10)
Growing interests in nitrogen-containing molecules involving bioactive and functional materials have stimulated the recent development of synthetic methodologies where nucleophilic addition reactions to imino carbons are utilized in crucial steps. This article summarizes double nucleophilic addition reactions with α,β-unsaturated aldimines, addition reactions using alkynyl imines, "umpoled" reactions of α-imino esters, and the use of iminium salts as reactive electrophiles. The Royal Society of Chemistry 2009.
N-allylideneamines derived from acrolein: synthesis and use as acceptors of two nucleophiles
Mizota, Isao,Matsuda, Yuri,Hachiya, Iwao,Shimizu, Makoto
experimental part, p. 4073 - 4084 (2009/12/26)
Two practical methods have been developed for the preparation of N-allylideneamines 1b,c. One involves the isomerlzation of propargylamines and the other the dehydration of acrolein. N-Allylideneamines 1b,c thus prepared, were used as efficient substrates
