1051945-72-2Relevant academic research and scientific papers
Ligand controlled highly regio- and enantioselective synthesis of α-acyloxyketones by palladium-catalyzed allylic alkylation of 1,2-enediol carbonates
Trost, Barry M.,Xu, Jiayi,Schmidt, Thomas
supporting information; experimental part, p. 11852 - 11853 (2009/02/05)
The palladium catalyzed decarboxylative asymmetric allylic alkylation of allyl 1,2-enediol carbonates 1 can decompose to either α-hydroxyketones 3 or α-hydroxyaldehydes 4. The product distribution is largely controlled by the ligand. Using Lnaph/sub
